tris(2-benzhydryl phenyl)boroxine

Base Information

• Chemical Name: tris(2-benzhydryl phenyl)boroxine
• CAS No.: 39777-45-2
• Molecular Formula: C₅₇H₄₅B₃O₃
• Molecular Weight: 810.415
• Mol file: 39777-45-2.mol

Synonyms:

Chemical Property of tris(2-benzhydryl phenyl)boroxine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tris(2-benzhydryl phenyl)boroxine

There total 3 articles about tris(2-benzhydryl phenyl)boroxine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-triphenylmethyl magnesium bromide + tri-n-butoxyboroxin (101-36-0) → tris(2-benzhydryl phenyl)boroxine (39777-45-2)

Guidance literature:

With hydrogenchloride; water; 2,2'-iminobis[ethanol]; In tetrahydrofuran; byproducts: H2O; react. of Grignard-compound and boroxine in THF, acidic hydrolysis, addn. of HN(CH2CH2OH)2, isolation of diethanol amine ester, hydrolysis; dehydration by sublimation in vac.;;

Reference yield:

2-(2-benzhydryl-phenyl)-[1,3,6,2]dioxazaborocane → tris(2-benzhydryl phenyl)boroxine (39777-45-2)

Guidance literature:

With hydrogenchloride; In toluene; Ambient temperature;

DOI:10.1016/S0022-328X(00)81597-1

Reference yield:

1-(2'-bromophenyl)-1,1-diphenylmethane (39777-52-1) → tris(2-benzhydryl phenyl)boroxine (39777-45-2)

Guidance literature:

Multi-step reaction with 2 steps

1: (i) Mg, THF, (ii) (nBuO)3B, (iii) /BRN= 605315/, toluene, H₂O

2: aq. HCl / toluene / Ambient temperature

With hydrogenchloride; In toluene;

DOI:10.1016/S0022-328X(00)81597-1

upstream raw materials:

1-(2'-bromophenyl)-1,1-diphenylmethane

tri-n-butoxyboroxin

Downstream raw materials:

9-chloro-10-phenyl-9,10-dihydro-9-boraanthracene

9-mesityl-10-phenyl-9-boraanthracene

10,10'-diphenyl-5,10,5',10'-tetrahydro-5,5'-oxy-bis-dibenzo[b,e]borinine

2-(10-phenyl-10H-dibenzo[b,e]borinin-5-yloxy)-ethylamine