2,4,6-Tributoxy-1,3,5,2,4,6-trioxatriborinane

Base Information

• Chemical Name: 2,4,6-Tributoxy-1,3,5,2,4,6-trioxatriborinane
• CAS No.: 101-36-0
• Molecular Formula: C12H27 B3 O6
• Molecular Weight: 299.776
• Hs Code.: 2934999090
• European Community (EC) Number: 600-197-9
• DSSTox Substance ID: DTXSID10402915
• Wikidata: Q82206436
• Mol file: 101-36-0.mol

Synonyms:2,4,6-tributoxy-1,3,5,2,4,6-trioxatriborinane;101-36-0;tributoxyboroxin;Boroxin, tributoxy-;starbld0019334;2,4,6-tributoxyboroxin;SCHEMBL2176779;DTXSID10402915;AKOS024322984

Chemical Property of 2,4,6-Tributoxy-1,3,5,2,4,6-trioxatriborinane

Chemical Property:

• Vapor Pressure: 0.001mmHg at 25°C
• Refractive Index: 1.406
• Boiling Point: 311.9°C at 760 mmHg
• Flash Point: 142.4°C
• PSA: 55.38000
• Density: 0.96g/cm³
• LogP: 2.45460
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 12
• Exact Mass: 300.2086791
• Heavy Atom Count: 21
• Complexity: 199

Purity/Quality:

99% ^*data from raw suppliers

2,4,6-TRIBUTOXY-1,3,5,2,4,6-TRIOXATRIBORINANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: B1(OB(OB(O1)OCCCC)OCCCC)OCCCC
• Uses: 2,?4,?6-?Tributoxyboroxin is a coupling agent used in the synthesis of gels and polymeric materials.

Technology Process of 2,4,6-Tributoxy-1,3,5,2,4,6-trioxatriborinane

There total 12 articles about 2,4,6-Tributoxy-1,3,5,2,4,6-trioxatriborinane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

boric acid tributyl ester (688-74-4) + Trimethylboroxine (823-96-1) → tri-n-butoxyboroxin (101-36-0) + methyldi-n-butoxyborane (86595-28-0)

Guidance literature:

In tetrahydrofuran; for 0.5h;

Reference yield:

tri-n-butylboroxine (7359-98-0) + oxygen (80937-33-3) → tri-n-butoxyboroxin (101-36-0)

Guidance literature:

Kinetics;

DOI:10.1039/j29710000698

Reference yield:

→ tri-n-butoxyboroxin (101-36-0)

Guidance literature:

With oxygen; hydroquinone;

upstream raw materials:

dibutoxy-chloro-borane

boric acid tributyl ester

iron(III) chloride

butyric acid

Downstream raw materials:

triethyl borane

triisobutylborane

tripropylborane

tris(2-benzhydryl phenyl)boroxine

Refernces

• 1、 Coffee,E.C.J.,Davies,A.G.. "-". . p. 1493 - 1496. Retrieved 1966.
• 2、 -. "PROCESS FOR SYNTHESIS OF DIALKOXYORGANOBORANES". Page/Page column 9. . Retrieved 2008/06/13.