(C₁₈H₁₈N₄)Fe(C₆H₅C(O)COO)⁽¹⁺⁾*ClO₄^(1-)*CH₃OH=[(C₁₈H₁₈N₄)Fe(C₆H₅C(O)COO)](ClO₄)*CH₃OH

Base Information

• Chemical Name: (C₁₈H₁₈N₄)Fe(C₆H₅C(O)COO)⁽¹⁺⁾*ClO₄^(1-)*CH₃OH=[(C₁₈H₁₈N₄)Fe(C₆H₅C(O)COO)](ClO₄)*CH₃OH
• CAS No.: 163236-08-6
• Molecular Formula: CH₄O*C₂₆H₂₃FeN₄O₃*ClO₄
• Molecular Weight: 626.833
• Mol file: 163236-08-6.mol

Synonyms:

Chemical Property of (C₁₈H₁₈N₄)Fe(C₆H₅C(O)COO)⁽¹⁺⁾*ClO₄^(1-)*CH₃OH=[(C₁₈H₁₈N₄)Fe(C₆H₅C(O)COO)](ClO₄)*CH₃OH

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (C₁₈H₁₈N₄)Fe(C₆H₅C(O)COO)⁽¹⁺⁾*ClO₄^(1-)*CH₃OH=[(C₁₈H₁₈N₄)Fe(C₆H₅C(O)COO)](ClO₄)*CH₃OH

There total 1 articles about (C₁₈H₁₈N₄)Fe(C₆H₅C(O)COO)⁽¹⁺⁾*ClO₄^(1-)*CH₃OH=[(C₁₈H₁₈N₄)Fe(C₆H₅C(O)COO)](ClO₄)*CH₃OH which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

iron(II) perchlorate hexahydrate + sodium benzoylformate (43165-51-1) + tris[(2-pyridylmethyl)amine] (16858-01-8) → (C18H18N4)Fe(C6H5C(O)COO)(1+)*ClO4(1-)*CH3OH=[(C18H18N4)Fe(C6H5C(O)COO)](ClO4)*CH3OH (163236-08-6)

Guidance literature:

With (C₂H₅)3N; In methanol; stirring (15 min, Ar atmosphere); filtn.;

Reference yield:

(C18H18N4)Fe(C6H5C(O)COO)(1+)*ClO4(1-)*CH3OH=[(C18H18N4)Fe(C6H5C(O)COO)](ClO4)*CH3OH (163236-08-6) → (C18H18N4)Fe(C6H5C(O)COO)(1+)*ClO4(1-)=[(C18H18N4)Fe(C6H5C(O)COO)]ClO4 (143294-11-5)

Guidance literature:

drying (vacuum); elem. anal.;

Reference yield:

[Fe(tris(2-pyridylmethyl)amine)(benzoylformate)(MeOH)](ClO4) (163236-08-6) + nitrogen(II) oxide (10102-43-9) → [Fe(tris(2-pyridylmethyl)amine)(benzoylformate)(NO)](ClO4)

Guidance literature:

In [D₃]acetonitrile; absence of air and moisture; bubbling NO through soln. of Fe-complex (room temp.); not isolated, reaction followed by (1)H-NMR spectroscopy;

DOI:10.1021/ic00116a020

upstream raw materials:

sodium benzoylformate

tris[(2-pyridylmethyl)amine]

Downstream raw materials:

(C₁₈H₁₈N₄)Fe(C₆H₅C(O)COO)⁽¹⁺⁾*ClO₄^(1-)=[(C₁₈H₁₈N₄)Fe(C₆H₅C(O)COO)]ClO₄

Refernces