(((CH₃)2NC₆H₄)2CHC₆H₃(COOH)(N(CH₃)2))2Ru₂Cl₄

Base Information

• Chemical Name: (((CH₃)2NC₆H₄)2CHC₆H₃(COOH)(N(CH₃)2))2Ru₂Cl₄
• CAS No.: 926919-85-9
• Molecular Formula: C₅₂H₆₂Cl₄N₆O₄Ru₂
• Molecular Weight: 1179.05
• Mol file: 926919-85-9.mol

Synonyms:

Chemical Property of (((CH₃)2NC₆H₄)2CHC₆H₃(COOH)(N(CH₃)2))2Ru₂Cl₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (((CH₃)2NC₆H₄)2CHC₆H₃(COOH)(N(CH₃)2))2Ru₂Cl₄

There total 1 articles about (((CH₃)2NC₆H₄)2CHC₆H₃(COOH)(N(CH₃)2))2Ru₂Cl₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

hydrogenchloride (7647-01-0,15364-23-5) + [(crystal violet lactone)Ru(η4-cod)] (926919-82-6) → (((CH3)2NC6H4)2CHC6H3(COOH)(N(CH3)2))2Ru2Cl4 (926919-85-9)

Guidance literature:

In hydrogenchloride; acetone; (inert conditions); addn. of 4 equiv. of 1 M aqueous HCl diluted with acetone (1:20) to soln. of ruthenium compd. in acetone at -78°C, stirring for 30 min at room temp.; evapn., washing with acetone and pentane, drying under vac., ESI-MS;

DOI:10.1016/j.jorganchem.2006.07.046

Reference yield: 57.0%

piperidine (110-89-4) + (((CH3)2NC6H4)2CHC6H3(COOH)(N(CH3)2))2Ru2Cl4 (926919-85-9) → (((CH3)2NC6H4)2CHC6H3(COOH)(N(CH3)2))RuCl2(C5H10NH) (926920-05-0)

Guidance literature:

In dichloromethane; (inert conditions); addn. of CH2Cl2 and piperidine to ruthenium compd., stirring for 2 h at room temp.; evapn., thin layer chromy. (silica gel, CH2Cl2-methanol (8.5:1)), NMR;

DOI:10.1016/j.jorganchem.2006.07.046

upstream raw materials:

hydrogenchloride

[(crystal violet lactone)Ru(η4-cod)]

Downstream raw materials:

(((CH₃)2NC₆H₄)2CHC₆H₃(COOH)(N(CH₃)2))RuCl₂(C₅H₁₀NH)

Refernces