Benzenecarboximidic acid, N-phenyl-, 2-phenylhydrazide

Base Information

• Chemical Name: Benzenecarboximidic acid, N-phenyl-, 2-phenylhydrazide
• CAS No.: 13136-18-0
• Molecular Formula: C19H17N3
• Molecular Weight: 287.364
• Mol file: 13136-18-0.mol

Synonyms:

Chemical Property of Benzenecarboximidic acid, N-phenyl-, 2-phenylhydrazide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzenecarboximidic acid, N-phenyl-, 2-phenylhydrazide

There total 21 articles about Benzenecarboximidic acid, N-phenyl-, 2-phenylhydrazide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.9%

benzoyl chloride (98-88-4) + aniline (62-53-3) + phenylhydrazine (100-63-0) → N,N'-diphenylbenzenecarbohydrazonamide (13136-18-0)

Guidance literature:

DOI:10.1016/j.inoche.2013.01.018

Reference yield: 39.0%

N-Phenyl-benzimidoyl-isothiocyanat (20800-27-5) + phenylhydrazine (100-63-0) → 1,3-Diphenyl-1,2,4-triazolin-thion-(5) (5055-73-2) + 1,5-diphenyl-1,2-dihydro-1,2,4-triazole-3-thione (5055-74-3) + β-(N-Phenyl-benzimidoyl)phenylhydrazin (13136-18-0)

Guidance literature:

In diethyl ether;

Reference yield: 38.0%

N-phenyl-benzimidoyl chloride (4903-36-0) + phenylhydrazine (100-63-0) → N',N''-diphenylbenzimidohydrazide (13136-18-0)

Guidance literature:

N-phenyl-benzimidoyl chloride; phenylhydrazine; With triethylamine; In tetrahydrofuran; at 0 - 20 ℃; for 48h;

With acetic acid; In water; at 20 ℃; for 0.25h;

DOI:10.1039/c9ob02258a

upstream raw materials:

N-phenyl-benzimidoyl chloride

phenylhydrazine

aniline

N-phenylbenzohydrazonoyl chloride

Downstream raw materials:

1,3,4-Triphenyl-1,2,4-triazabutadien

Δ5-2,3,4,5-tetraphenyl-1,2,4,3-triazaborolane

1,3,4-triphenyl-1,2,4-triazolium chloride

RuCl₂(N,N-diphenylbenzenecarbohydrazonamide(-2H))(5-amino-1,10-phenanthroline)

Refernces

• 1、 Beillard, Audrey,Bantreil, Xavier,Métro, Thomas-Xavier,Martinez, Jean,Lamaty, Frédéric. "Mechanochemistry for facilitated access to N,N-diaryl NHC metal complexes". . p. 1057 - 1063. Retrieved 2017.
• 2、 Draskovits, Markus,Kalaus, Hubert,Stanetty, Christian,Mihovilovic, Marko D.. "Intercepted dehomologation of aldoses by N-heterocyclic carbene catalysis-a novel transformation in carbohydrate chemistry". . p. 12144 - 12147. Retrieved 2019/10/21.