Benzene, [(2-propenylsulfinyl)methyl]-

Base Information

• Chemical Name: Benzene, [(2-propenylsulfinyl)methyl]-
• CAS No.: 13284-96-3
• Molecular Formula: C10H12OS
• Molecular Weight: 180.271
• Mol file: 13284-96-3.mol

Synonyms:

Chemical Property of Benzene, [(2-propenylsulfinyl)methyl]-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzene, [(2-propenylsulfinyl)methyl]-

There total 5 articles about Benzene, [(2-propenylsulfinyl)methyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

allyl(benzyl)sulfide (6937-97-9) → 2-propenyl benzyl sulfoxide (13284-96-3)

Guidance literature:

With nitric acid; tetrabutylammonium tetrabromoaurate(III); In nitromethane; for 2h; Ambient temperature;

DOI:10.1021/jo00291a043

Reference yield: 86.0%

allyl(benzyl)sulfide (6937-97-9) → ((allylsulfonyl)methyl)benzene (6633-92-7) + 2-propenyl benzyl sulfoxide (13284-96-3)

Guidance literature:

With immobilised lipase B from Candida antarctica; urea hydrogen peroxide adduct; ethyl acetate; at 37 ℃; for 24h; chemoselective reaction; Enzymatic reaction;

DOI:10.1039/d0ob01966f

Reference yield:

phenylmethanethiol (100-53-8) → ((allylsulfonyl)methyl)benzene (6633-92-7) + 2-propenyl benzyl sulfoxide (13284-96-3)

Guidance literature:

Multi-step reaction with 2 steps

1: potassium carbonate; sodium iodide / water / 140 °C / Microwave irradiation

2: immobilised lipase B from Candida antarctica; urea hydrogen peroxide adduct; ethyl acetate / 24 h / 37 °C / Enzymatic reaction

With immobilised lipase B from Candida antarctica; urea hydrogen peroxide adduct; potassium carbonate; ethyl acetate; sodium iodide; In water;

DOI:10.1039/d0ob01966f

upstream raw materials:

allyl(benzyl)sulfide

methyl phenylmethanesulfinate

phenylmethanethiol

Downstream raw materials:

allyl(benzyl)sulfide

((allylsulfonyl)methyl)benzene

Refernces

• 1、 Back, Thomas G.,Moussa, Ziad. "Diselenides and Allyl Selenides as Glutathione Peroxidase Mimetics. Remarkable Activity of Cyclic Seleninates Produced in Situ by the Oxidation of Allyl ω-Hydroxyalkyl Selenides". . p. 13455 - 13460. Retrieved 2003.
• 2、 Kobayashi, Akihiro,Matsuzawa, Tsubasa,Hosoya, Takamitsu,Yoshida, Suguru. "Sulfoxide synthesis from sulfinate esters under Pummerer-like conditions". . p. 5429 - 5432. Retrieved 2020/06/04.