Thiopyrylium, 4-methyl-2,6-diphenyl-, perchlorate

Base Information

• Chemical Name: Thiopyrylium, 4-methyl-2,6-diphenyl-, perchlorate
• CAS No.: 13586-30-6
• Molecular Formula: C18H15S.ClO4
• Molecular Weight: 362.834
• Mol file: 13586-30-6.mol

Synonyms:

Chemical Property of Thiopyrylium, 4-methyl-2,6-diphenyl-, perchlorate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Thiopyrylium, 4-methyl-2,6-diphenyl-, perchlorate

There total 3 articles about Thiopyrylium, 4-methyl-2,6-diphenyl-, perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,6-diphenyl-4H-thiopyran-4-one (1029-96-5) + methylmagnesium bromide (75-16-1) → 2,6-diphenyl-4-(methyl)thiopyrylium perchlorate (13586-30-6)

Guidance literature:

With diethyl ether; benzene; Umsetzung des Reaktionsprodukts mit Perchlorsaeure;

DOI:10.1002/hlca.19560390124

Reference yield:

3-methyl-1,5-diphenyl-pentane-1,5-dione (1226-91-1) → 2,6-diphenyl-4-(methyl)thiopyrylium perchlorate (13586-30-6)

Guidance literature:

With perchloric acid; hydrogen sulfide; Ambient temperature;

DOI:10.1007/BF00663518

Reference yield:

→ 2,6-diphenyl-4-(methyl)thiopyrylium perchlorate (13586-30-6)

Guidance literature:

2.6-Diphenyl-tetrahydrothiopyron in Benzol, 1)Methylmagnesiumiodid/Et2O b. Siedetemp. 2) Triphenylmethan/HOAc, Perchlorsaeure b. Siedetemp.;

upstream raw materials:

2,6-diphenyl-4H-thiopyran-4-one

methylmagnesium bromide

3-methyl-1,5-diphenyl-pentane-1,5-dione

Downstream raw materials:

4-Methoxy-4-methyl-2,6-diphenyl-4H-thiopyran

2-Methoxy-4-methyl-2,6-diphenyl-2H-thiopyran

4,4'-(ethandilyden)-bis[(2,6-diphenyl)-4H-thiapyran]

(4-methyl-2,6-diphenyl-4H-thiopyran-4-yl)triethoxyphosphonium perchlorate

Refernces

• 1、 Wizinger,Ulrich. "-". . p. 207,214. Retrieved 1956.