2-linoleoyl glycerol

Base Information

• Chemical Name: 2-linoleoyl glycerol
• CAS No.: 126392-16-3
• Molecular Formula: C₂₁H₃₈O₄
• Molecular Weight: 354.53
• Mol file: 126392-16-3.mol

Synonyms:

Chemical Property of 2-linoleoyl glycerol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-linoleoyl glycerol

There total 6 articles about 2-linoleoyl glycerol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

2-((9Z,12Z)-octadeca-9,12-dienoyloxy)propane-1,3-diyl dibutyrate (402562-28-1) → 2-linoleoyl glycerol (126392-16-3,3443-82-1)

Guidance literature:

With Rhizomucor miehei lipase; ethanol; at 20 ℃; for 24h; regiospecific reaction; Enzymatic reaction;

DOI:10.1016/j.tet.2012.04.101

Reference yield: 65.7%

1,2,3-tri(cis,cis-9,12-octadecadienoyloxy)propane (537-40-6) → 2-linoleoyl glycerol (126392-16-3,3443-82-1)

Guidance literature:

With Novozym 435; ethanol; at 25 ℃; for 4h; Enzymatic reaction;

DOI:10.1007/s11746-012-2113-z

Reference yield:

linoleyl chloride (7459-33-8) → 2-linoleoyl glycerol (126392-16-3,3443-82-1)

Guidance literature:

With pyridine; chloroform; Erhitzen des Reaktionsprodukts mit Triaethylborat und Borsaeure und Behandeln einer Loesung des danach isolierten Reaktionsprodukts in Aether mit Wasser;

DOI:10.1021/ja01118a004

upstream raw materials:

2-O-(9,10,12,13-Tetrabromstearoyl)-glycerin

linoleyl chloride

5-<9,10,12,13-Tetrabrom-stearoyloxy>-2-phenyl-<1,3>dioxan

2-((9Z,12Z)-octadeca-9,12-dienoyloxy)propane-1,3-diyl dibutyrate

Downstream raw materials:

1-monolinoleoyl-rac-glycerol

1-olein-2-linolein

Refernces

• 1、 Compton, David L.,Laszlo, Joseph A.,Appell, Michael,Vermillion, Karl E.,Evans, Kervin O.. "Influence of fatty acid desaturation on spontaneous acyl migration in 2-monoacylglycerols". . p. 2259 - 2267. Retrieved 2013/01/15.