[Ru(C₅H₅)(P(C₆H₅)3)(C₅H₅N)Br]

Base Information

• Chemical Name: [Ru(C₅H₅)(P(C₆H₅)3)(C₅H₅N)Br]
• CAS No.: 97286-22-1
• Molecular Formula: C₂₈H₂₅BrNPRu
• Molecular Weight: 587.461
• Mol file: 97286-22-1.mol

Synonyms:

Chemical Property of [Ru(C₅H₅)(P(C₆H₅)3)(C₅H₅N)Br]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ru(C₅H₅)(P(C₆H₅)3)(C₅H₅N)Br]

There total 1 articles about [Ru(C₅H₅)(P(C₆H₅)3)(C₅H₅N)Br] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[(η5-cyclopentadienyl)Ru(PPh3)2Br] (32993-06-9) → [Ru(C5H5)(P(C6H5)3)(C5H5N)Br] (97286-22-1)

Guidance literature:

With pyridine; In pyridine; (Ru(η-C5H5)(PPh3)2Br) heated under reflux for 10 h in pyridine under N2 atm.; crystals centrifuged, washed with ethanol, water, ethanol and diethyl ether and dried in vacuo and recrystd. from CH2Cl2/light petroleum (40-60°C); elem. anal.;

DOI:10.1016/S0020-1693(00)87599-4

Reference yield:

[Ru(C5H5)(P(C6H5)3)(C5H5N)Br] (97286-22-1) + nitrosylchloride (2696-92-6) → (Ru(NO)(P(C6H5)3)(NC5H5)Cl2Br)

Guidance literature:

In dichloromethane; to soln. (Ru(η5-C5H5)(PPh3)(Py)Br) in CH2Cl2 saturated soln. NOCl in CH2Cl2 added and mixt. stirred for 30 min under N2 atm.; mixt. concd. under reduced pressure, soln. filtered, n-hexane added, products filtered, washed with petroleum ether (40-60°C) and dried under vac.; elem. anal.;

DOI:10.1016/S0020-1693(00)87600-8

Reference yield:

[Ru(C5H5)(P(C6H5)3)(C5H5N)Br] (97286-22-1) + nitrosyl bromide (13444-87-6) → [Ru(NO)(P(C6H5)3)(C5H5N)Br3] (97263-25-7)

Guidance literature:

In dichloromethane; to soln. (Ru(η5-C5H5)(PPh3)(Py)Br) in CH2Cl2 saturated soln. NOBr in CH2Cl2 added and mixt. stirred for 30 min under N2 atm.; mixt. concd. under reduced pressure, soln. filtered, n-hexane added, products filtered, washed with petroleum ether (40-60°C) and dried under vac.; elem. anal.;

DOI:10.1016/S0020-1693(00)87600-8

upstream raw materials:

[(η5-cyclopentadienyl)Ru(PPh3)2Br]

Downstream raw materials:

[Ru(NO)(P(C₆H₅)3)(C₅H₅N)Br₃]