32993-06-9Relevant articles and documents
Halogen exchange by reaction of CpRu(Cl)(PPh3)2 with MeC(O)X (X = Br, I) and its mechanistic study
Kuniyasu, Hitoshi,Sanagawa, Atsushi,Nakajima, Takuya,Iwasaki, Takanori,Kambe, Nobuaki,Bobuatong, Karan,Ehara, Masahiro
, p. 34 - 37 (2014)
The treatment of CpRu(Cl)(PPh3)2 with MeC(O)X offers a very convenient procedure for the synthesis of CpRu(X)(PPh3) 2. The proposed mechanism involves an intermediate produced by the concerted liberation of PPh3 by the incoming MeC(O)X and the subsequent subtraction of the X atom by the Ru atom to form a radical pair.
Acid-promoted sp3 C-H bond cleavage in a series of (2-allylphenoxo) ruthenium(II) complexes. Mechanistic insight into the aryloxo-acid interaction and bond cleavage reaction
Hirano, Masafumi,Murakami, Masahiro,Kuga, Toshinori,Komine, Nobuyuki,Komiya, Sanshiro
, p. 381 - 393 (2012/05/07)
A series of RuCp[OC6H3(CH2CH=CH 2-2)(R)](PPh3)n complexes (n = 2, R = H (1a); n = 1, R = 4-OMe (2b), 4-Me (2c), 4-Ph (2d), 4-Br (2e), 4-NO2 (2f), 6-OMe (2g), 6-Me (2h), 6-Ph (2i)) have been
Reactions of Transition Metal o-Acetylide Complexes. XIII. Alkylation and Related Reactions
Bruce, Michael I.,Humphrey, Mark G.
, p. 1067 - 1076 (2007/10/02)
A series of 20 cationic vinylidene complexes of ruthenium and osmium + (R = Me, Ph, C6H4F-4, C6F5, (CH2)2C2H; R' = Me, CH2Ph, CH2CH=CH2, CH2CCH, (CH2)3Br; L, L' = PPh3, CNBut, dppm, dppe; not all combinations)., 2>2+ and 2>2+ have been obtained from reactions between the metal acetylide complexes and the appropriate organic halides.
