1422584-32-4

Basic information

• Product Name: [(η⁵-C₅H₅)RuBr(PPh₃)(TPH)]
• CAS NO: 1422584-32-4
• Molecular Weight: 655.581
• Mol File: 1422584-32-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(η⁵-C₅H₅)RuBr(PPh₃)(TPH)](CAS DataBase Reference)
• NIST Chemistry Reference: [(η⁵-C₅H₅)RuBr(PPh₃)(TPH)](1422584-32-4)
• EPA Substance Registry System: [(η⁵-C₅H₅)RuBr(PPh₃)(TPH)](1422584-32-4)

Safety Data

• Hazardous Substances Data: 1422584-32-4(Hazardous Substances Data)

Upstream product

• 32993-06-9 [(η5-cyclopentadienyl)Ru(PPh3)2Br] 
• 1986-38-5 2-thioxopherhydro-1,3-thiazine-4-one 

Relevant articles and documents

Reactions of 2-thioxoper hydro-1, 3-thiazin-4 ones with cyclopentadienyl - Ruthenium II, dicarbonyldichloro ruthenium II complexes and tetra carbonyldi-μ-halodirhodium

In this paper, the reaction of 2-thioxopherhydro-1, 3-thiazine-4 ones with [Ru(η5-C5H5) (PPh3) 2X] (X=CI, Br, I), [Ru(η5--C5H5) (MPh3)2 CI] (M = As, Sb) and [Ru(CO)2 Cl 2] complexes lead to the formations of [Ru(η5-C 5H5) (PPh3) (TPH)X] (X=CI, Br, I), [Ru( 5-C5H5) (MPη3 (TPH) Cl] (M=As, Sb) [Ru(CO)2 CI2(TPH)] and [Rh(CO)2 X(TPH)] (X=CI, Br) The compounds have been characterised by analytical, magnetic, conductivity and spectroscopic (ir, uv and visible) studies and a quasioctahedral geometry is proposed for Ru(II) complexes and square planar geometry for Rh(I) Complexes.