[(Ph₃P)2Ag(H₂cit)]*EtOH

Base Information

• Chemical Name: [(Ph₃P)2Ag(H₂cit)]*EtOH
• CAS No.: 1370733-78-0
• Molecular Formula: C₂H₆O*C₄₂H₃₇AgO₇P₂
• Molecular Weight: 869.636
• Mol file: 1370733-78-0.mol

Synonyms:

Chemical Property of [(Ph₃P)2Ag(H₂cit)]*EtOH

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of [(Ph₃P)2Ag(H₂cit)]*EtOH

There total 3 articles about [(Ph₃P)2Ag(H₂cit)]*EtOH which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

ethanol (64-17-5) + silver(I) citrate (126-45-4) + citric acid monohydrate (5949-29-1) + triphenylphosphine (603-35-0) → [(Ph3P)2Ag(H2cit)]*EtOH (1370733-78-0)

Guidance literature:

In ethanol; mixt. Ag3cit, citric acid monohydrate, PPh3 and EtOH was heated with stirring; soln. was filtered hot and allowed to cool slowly, ppt. was colledcted and washed with ice-cold EtOH; elem. anal.;

DOI:10.1039/c2dt12452a

Reference yield:

ethanol (64-17-5) + [(Ph3P)2Ag(H2cit)] (1370733-77-9) → [(Ph3P)2Ag(H2cit)]*EtOH (1370733-78-0)

Guidance literature:

In neat (no solvent, solid phase); grinding with EtOH followed air-drying;

DOI:10.1039/c2dt12452a

Reference yield:

ethanol (64-17-5) + citric acid monohydrate (5949-29-1) + triphenylphosphine (603-35-0) + silver(l) oxide (20667-12-3) → [(Ph3P)2Ag(H2cit)]*EtOH (1370733-78-0)

Guidance literature:

In neat (no solvent, solid phase); Ag2O and citric acid monohydrate were ground together, PPh3 was added, EtOH was added, grinded and heated at 50°C for 30 min;

DOI:10.1039/c2dt12452a

upstream raw materials:

ethanol

silver(I) citrate

citric acid monohydrate

triphenylphosphine

Downstream raw materials:

[(Ph₃P)2Ag(H₂cit)]

Refernces