trimeric cis-(methylamino)borane

Base Information

• Chemical Name: trimeric cis-(methylamino)borane
• CAS No.: 60619-50-3
• Molecular Formula: C₃H₁₈B₃N₃
• Molecular Weight: 128.629
• Mol file: 60619-50-3.mol

Synonyms:

Chemical Property of trimeric cis-(methylamino)borane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trimeric cis-(methylamino)borane

There total 12 articles about trimeric cis-(methylamino)borane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

methylamine-borane (1722-33-4) → N,N',N''-trimethylborazane (60619-50-3,60619-49-0,14708-83-9) + hydrogen (1333-74-0)

Guidance literature:

In neat (no solvent); at 100°C, discussion of react. mechanism;;

Reference yield: 82.7%

{CH3H2NBH2NHCH3BH2NH2CH3}(1+)*BH4(1-)={CH3H2NBH2NHCH3BH2NH2CH3}BH4 → N,N',N''-trimethylborazane (60619-50-3,60619-49-0,14708-83-9) + 1,3,5-trimethyl-cyclotriborazane (1004-35-9)

Guidance literature:

100°C, 2 h;

Reference yield: 48.0%

sodium tetrahydroborate (16940-66-2) + N-trimethylborazine (trishydrochloride) → N,N',N''-trimethylborazane (60619-50-3,60619-49-0,14708-83-9) + diborane (19287-45-7)

Guidance literature:

byproducts: NaCl; 100°C in vac.;

DOI:10.1021/ja00887a006

upstream raw materials:

methylamine-borane

sodium tetrahydroborate

[Rh(P(cyclo-C5H9)2(η2-C5H7))(η1:η1:η1-(H2BNMeH)3)][BAr(F)4]

acetonitrile

Downstream raw materials:

[Rh(P(cyclo-C5H9)2(η2-C5H7))(η1:η1:η1-(H2BNMeH)3)][BAr(F)4]

1,3,5-trimethyl-cyclotriborazane

(methylamino)bromoborane

hydrogen bromide

Refernces

• 1、 Robertson, Alasdair P. M.,Leitao, Erin M.,Jurca, Titel,Haddow, Mairi F.,Helten, Holger,Lloyd-Jones, Guy C.,Manners, Ian. "Mechanisms of the thermal and catalytic redistributions, oligomerizations, and polymerizations of linear diborazanes". supporting information. p. 12670 - 12683. Retrieved 2013/09/23.
• 2、 Robertson, Alasdair P. M.,Leitao, Erin M.,Manners, Ian. "Catalytic redistribution and polymerization of diborazanes: Unexpected observation of metal-free hydrogen transfer between aminoboranes and amine-boranes". . p. 19322 - 19325. Retrieved 2012/01/13.