Sodium;trisilylsilanide

Base Information

• Chemical Name: Sodium;trisilylsilanide
• CAS No.: 139508-57-9
• Molecular Formula: H9NaSi4
• Molecular Weight: 144.403
• DSSTox Substance ID: DTXSID00576290
• Mol file: 139508-57-9.mol

Synonyms:

Chemical Property of Sodium;trisilylsilanide

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 143.96790071
• Heavy Atom Count: 5
• Complexity: 8.4

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [Na+].[SiH3][Si-]([SiH3])[SiH3]

Technology Process of Sodium;trisilylsilanide

There total 1 articles about Sodium;trisilylsilanide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.6%

monosilane (7440-21-3) → sodium disilanyl (139508-55-7) + 2-sodium trisilanyl (139508-56-8) + 2-sodium isotetrasilanyl (139508-57-9) + sodium hydride (7646-69-7) + sodiumsilanyl

Guidance literature:

With sodium; In diethylene glycol; Under N2, filling of SiH4 in an evacuated flask with a freshly prepd. Na dispersion at -30 or 25°C under magnetic stirring. End of react. is reached after 3 days.; Concg. in vac. under stirring, filtn. (NaH), addn. of benzylchloride, GC.;

upstream raw materials:

monosilane