AuC₆F₅(P(C₆H₅)2CC)Au(C₆F₅)^(1-)*N(P(C₆H₅)3)2⁽¹⁺⁾=Au₂(C₆F₅)2P(C₆H₅)2CC(N(P(C₆H₅)3)2)

Base Information

• Chemical Name: AuC₆F₅(P(C₆H₅)2CC)Au(C₆F₅)^(1-)*N(P(C₆H₅)3)2⁽¹⁺⁾=Au₂(C₆F₅)2P(C₆H₅)2CC(N(P(C₆H₅)3)2)
• CAS No.: 497065-02-8
• Molecular Formula: C₂₆H₁₀Au₂F₁₀P*C₃₆H₃₀NP₂
• Molecular Weight: 1475.84
• Mol file: 497065-02-8.mol

Synonyms:

Chemical Property of AuC₆F₅(P(C₆H₅)2CC)Au(C₆F₅)^(1-)*N(P(C₆H₅)3)2⁽¹⁺⁾=Au₂(C₆F₅)2P(C₆H₅)2CC(N(P(C₆H₅)3)2)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of AuC₆F₅(P(C₆H₅)2CC)Au(C₆F₅)^(1-)*N(P(C₆H₅)3)2⁽¹⁺⁾=Au₂(C₆F₅)2P(C₆H₅)2CC(N(P(C₆H₅)3)2)

There total 3 articles about AuC₆F₅(P(C₆H₅)2CC)Au(C₆F₅)^(1-)*N(P(C₆H₅)3)2⁽¹⁺⁾=Au₂(C₆F₅)2P(C₆H₅)2CC(N(P(C₆H₅)3)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

bis(triphenylphosphane)iminium(pentafluorophenyl)chlorogold(I) (74558-90-0) + AuC6F5(P(C6H5)2CCH) (497064-99-0) → AuC6F5(P(C6H5)2CC)Au(C6F5)(1-)*N(P(C6H5)3)2(1+)=Au2(C6F5)2P(C6H5)2CC(N(P(C6H5)3)2) (497065-02-8)

Guidance literature:

With NaOMe; In methanol; NaOMe was added to MeOH soln. of Au(C6F5)(PPh2CCH), stirred for 2 h, Au-complex was added, stirred for 1 h under inert atm.; solvent was removed, CH2Cl2 was added, filtered, evapd. to dryness; elem. anal.;

Reference yield:

ethynyldiphenylphosphine (6104-47-8) → AuC6F5(P(C6H5)2CC)Au(C6F5)(1-)*N(P(C6H5)3)2(1+)=Au2(C6F5)2P(C6H5)2CC(N(P(C6H5)3)2) (497065-02-8)

Guidance literature:

Multi-step reaction with 2 steps

1: dichloromethane

2: NaOMe / methanol

With NaOMe; In methanol; dichloromethane;

Reference yield:

pentafluorophenyl(tetrahydrothiophene)gold(I) → AuC6F5(P(C6H5)2CC)Au(C6F5)(1-)*N(P(C6H5)3)2(1+)=Au2(C6F5)2P(C6H5)2CC(N(P(C6H5)3)2) (497065-02-8)

Guidance literature:

Multi-step reaction with 2 steps

1: dichloromethane

2: NaOMe / methanol

With NaOMe; In methanol; dichloromethane;

upstream raw materials:

bis(triphenylphosphane)iminium(pentafluorophenyl)chlorogold(I)

AuC₆F₅(P(C₆H₅)2CCH)

ethynyldiphenylphosphine

Refernces