C₉H₁₃BrClNSSi

Base Information

• Chemical Name: C₉H₁₃BrClNSSi
• CAS No.: 157736-04-4
• Molecular Formula: C₉H₁₃BrClNSSi
• Molecular Weight: 310.717
• Mol file: 157736-04-4.mol

Synonyms:

Chemical Property of C₉H₁₃BrClNSSi

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₉H₁₃BrClNSSi

There total 2 articles about C₉H₁₃BrClNSSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N-(trimethylsilyl)-4-bromoaniline (63911-87-5) → C9H13BrClNSSi (157736-04-4)

Guidance literature:

With sulfur dichloride; triethylamine; In diethyl ether; 0.5 h, -10 degC, allowed to warm to 20 degC over 1 h;

DOI:10.1016/S0040-4039(00)77083-3

Reference yield:

4-bromo-aniline (106-40-1) → C9H13BrClNSSi (157736-04-4)

Guidance literature:

Multi-step reaction with 2 steps

1: diethyl ether / 16 h / 20 °C

2: Et₃N, SCl₂ / diethyl ether / 1.) -10 deg C, 0.5 h, 2.) -10 to 20 deg C, 0.5 h

With sulfur dichloride; triethylamine; In diethyl ether;

DOI:10.1039/p19960001825

Reference yield:

2,3-dimethyl-buta-1,3-diene (513-81-5) + C9H13BrClNSSi (157736-04-4) → 2-(4-bromo-phenyl)-4,5-dimethyl-3,6-dihydro-2H-[1,2]thiazine (13616-71-2) + N-(4-bromophenyl)-3-methyl-2-methylenebut-3-ene-1-sulphenamide (118623-13-5)

Guidance literature:

In acetonitrile; at 20 ℃; for 16h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1016/S0040-4039(00)77083-3 DOI:10.1039/p19960001825

upstream raw materials:

N-(trimethylsilyl)-4-bromoaniline

4-bromo-aniline

Downstream raw materials:

2-(4-bromo-phenyl)-4,5-dimethyl-3,6-dihydro-2H-[1,2]thiazine

N-(4-bromophenyl)-3-methyl-2-methylenebut-3-ene-1-sulphenamide

trans-(+/-)-2-(4-bromophenyl)-3,6-dimethyl-3,6-dihydro-2H-1,2-thiazine

Refernces

• 1、 Bryce,Chesney,Heaton,McKelvey,Anderson. "Alkylthionitroso and arylthionitroso compounds generated from N- trimethylsilyl-N-chlorothioalkylamine precursors". . p. 5275 - 5278. Retrieved 2007/10/02.