trans-phenylsulfur chlorotetrafluoride

Base Information

• Chemical Name: trans-phenylsulfur chlorotetrafluoride
• CAS No.: 1063625-79-5
• Molecular Formula: C₆H₅ClF₄S
• Molecular Weight: 220.618
• Mol file: 1063625-79-5.mol

Synonyms:

Chemical Property of trans-phenylsulfur chlorotetrafluoride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of trans-phenylsulfur chlorotetrafluoride

There total 20 articles about trans-phenylsulfur chlorotetrafluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

diphenyldisulfane (882-33-7) → phenyltetrafluoro-λ6-sulfanyl chloride (203126-16-3,203210-31-5,1063625-79-5)

Guidance literature:

With potassium fluoride; chlorine; In acetonitrile; Product distribution / selectivity; Inert atmosphere; Cooling with ice;

Reference yield: 88.0%

diphenyldisulfane (882-33-7) → trans-phenylsulfur chlorotetrafluoride (1063625-79-5,203126-16-3,203210-31-5)

Guidance literature:

With potassium fluoride; chlorine; In acetonitrile; at 0 - 5 ℃; for 9.5h; Product distribution / selectivity;

Reference yield: 84.0%

phenylsulphur trifluoride (672-36-6) → phenyltetrafluoro-λ6-sulfanyl chloride (203126-16-3,203210-31-5,1063625-79-5)

Guidance literature:

With chlorine; cesium fluoride; In acetonitrile; at 6 - 9 ℃; for 0.7h; Product distribution / selectivity;

upstream raw materials:

diphenyldisulfane

thiophenol

phenylsulphur trifluoride

methyl-phenyl-thioether

Downstream raw materials:

pentafluorosulfanylbenzene

cis-phenylsulfur chlorotetrafluoride

phenylsulfonyl fluoride

2-(Phenyltetrafluoro-λ 6-sulfanyl)ethynylbenzene

Refernces

• 1、 Fetyukhin, Volodymyr N.,Guzyr, Olexandr I.,Kozel, Volodymyr N.,Rozhenko, Olexandr B.,Rusanov, Eduard B.,Shermolovich, Yuriy G.. "Enhanced preparation of aryl and heteryl sulfur pentafluorides using mercury (II) oxide - hydrogen fluoride media as a fluorinating reagent". . . Retrieved 2020.
• 2、 Wang, Lin,Ni, Shengyang,Cornella, Josep. "Validation of Arylphosphorothiolates as Convergent Substrates for Ar-SF 4Cl and Ar-SF 5Synthesis". supporting information. p. 4308 - 4312. Retrieved 2021/06/02.