Methoxydimethylvinylsilane

Base Information

• Chemical Name: Methoxydimethylvinylsilane
• CAS No.: 16546-47-7
• Molecular Formula: C5H12 O Si
• Molecular Weight: 116.235
• Hs Code.: 2931900090
• European Community (EC) Number: 240-615-3
• DSSTox Substance ID: DTXSID10937090
• Nikkaji Number: J318.243F
• Wikidata: Q82913291
• Mol file: 16546-47-7.mol

Synonyms:16546-47-7;Methoxydimethylvinylsilane;DIMETHYLVINYLMETHOXYSILANE;ethenyl-methoxy-dimethylsilane;Silane, ethenylmethoxydimethyl-;Methoxydimethyl(vinyl)silane;ethenyl(methoxy)dimethylsilane;vinyldimethylmethoxysilane;methoxyvinyldimethylsilane;dimethyl methylvinyl siloxane;dimethyl-vinyl-methoxy-silane;SCHEMBL62302;Ethenyl dimethyl(methoxy)silane;Vinyldimethylmethoxysilane, 95%;DTXSID10937090;Dimethyl(vinyl)silyl methyl ether #;EINECS 240-615-3;MFCD01074481;AKOS006275029;FT-0695084;F87166

Chemical Property of Methoxydimethylvinylsilane

Chemical Property:

• Vapor Pressure: 176mmHg at 25°C
• Boiling Point: 64.6°C at 760 mmHg
• PSA: 9.23000
• Density: 0.783g/cm³
• LogP: 1.56310
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 116.065741536
• Heavy Atom Count: 7
• Complexity: 68.5

Purity/Quality:

98%,99%, ^*data from raw suppliers

DIMETHYLVINYLMETHOXYSILANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CO[Si](C)(C)C=C

Technology Process of Methoxydimethylvinylsilane

There total 7 articles about Methoxydimethylvinylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

chloromethyldimethylvinylsilane (16709-86-7) + sodium methylate (124-41-4) → dimethyldimethoxysilan (1112-39-6) + vinyldimethylmonomethoxysilane (16546-47-7) + allyl(methoxy)dimethylsilane (30535-30-9) + (methoxymethyl)dimethylvinylsilane (98582-92-4)

Guidance literature:

In methanol; at 65 ℃; Yields of byproduct given;

DOI:10.1016/S0040-4039(00)98411-9

Reference yield: 47.0%

methanol (67-56-1) + Chlorodimethylvinylsilane (1719-58-0) → vinyldimethylmonomethoxysilane (16546-47-7)

Guidance literature:

In dichloromethane; at 50 ℃;

DOI:10.1007/BF00698510

Reference yield: 45.0%

chloromethyldimethylvinylsilane (16709-86-7) + sodium methylate (124-41-4) → dimethyldimethoxysilan (1112-39-6) + vinyldimethylmonomethoxysilane (16546-47-7) + allyl(methoxy)dimethylsilane (30535-30-9)

Guidance literature:

In 1,4-dioxane; at 100 ℃;

DOI:10.1016/S0040-4039(00)98411-9

upstream raw materials:

Chlorodimethylvinylsilane

trimethyl orthoformate

methanol

chloromethyldimethylvinylsilane

Refernces

• 1、 Jones,P.R. et al.. "-". . p. 99 - 110. Retrieved 1978.
• 2、 Lakhtin, V. G.,Ryabkov, V. L.,Polyakova, M. V.,Nosova, V. M.,Kisin, A. V.,Chernyshev, E. A.. "Alkoxylation of C-chlorovinylsilanes". . p. 718 - 723. Retrieved 2007/10/02.
• 3、 Bertrand, G.,Manuel, G.,Mazerolles, P.,Trinquier, G.. "LE PROBLEME DE LA CONJUGAISON A TRAVERS UN ATOME DE SILICIUM ?-LIE DANS LES SYSTEMES SILA-2 BUTADIENIQUES". . p. 2875 - 2880. Retrieved 2007/10/02.