C₂₆H₃₂Cl₂N₂Rh₂S

Base Information

• Chemical Name: C₂₆H₃₂Cl₂N₂Rh₂S
• CAS No.: 134067-03-1
• Molecular Formula: C₂₆H₃₂Cl₂N₂Rh₂S
• Molecular Weight: 681.336
• Mol file: 134067-03-1.mol

Synonyms:

Chemical Property of C₂₆H₃₂Cl₂N₂Rh₂S

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of C₂₆H₃₂Cl₂N₂Rh₂S

There total 1 articles about C₂₆H₃₂Cl₂N₂Rh₂S which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium (12092-47-6) + di-2-pyridyl sulfide (4262-06-0) → C26H32Cl2N2Rh2S (134067-03-1,134067-02-0) + {(Rh(C8H12)Cl)2((C5H4N)2S)}*0.5(C6H5)CH3

Guidance literature:

In toluene; at -5°C;; washing with toluene and diethyl ether; cooling overnight in a freezer; drying in vacuo over P4O10; elem. anal.;;

DOI:10.1039/DT9910000425

Reference yield:

di-2-pyridyl sulfide (4262-06-0) + C26H32Cl2N2Rh2S (134067-03-1,134067-02-0) → {Rh(C8H12)((C5H4N)2S)}(1+)*{B(C6H5)4}(1-)={Rh(C8H12)((C5H4N)2S)}{B(C6H5)4} (134067-05-3)

Guidance literature:

Multi-step reaction with 2 steps

1: not given

2: not given

In not given;

DOI:10.1039/DT9910000425

upstream raw materials:

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

di-2-pyridyl sulfide

Downstream raw materials:

{Rh(C₈H₁₂)((C₅H₄N)2S)}⁽¹⁺⁾*{B(C₆H₅)4}^(1-)={Rh(C₈H₁₂)((C₅H₄N)2S)}{B(C₆H₅)4}

Refernces