{Ru(C₂H₅O₂CC₆H₄NCHC₆H₄O)3}

Base Information

• Chemical Name: {Ru(C₂H₅O₂CC₆H₄NCHC₆H₄O)3}
• CAS No.: 111267-20-0
• Molecular Formula: C₄₈H₄₂N₃O₉Ru
• Molecular Weight: 905.946
• Mol file: 111267-20-0.mol

Synonyms:

Chemical Property of {Ru(C₂H₅O₂CC₆H₄NCHC₆H₄O)3}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of {Ru(C₂H₅O₂CC₆H₄NCHC₆H₄O)3}

There total 1 articles about {Ru(C₂H₅O₂CC₆H₄NCHC₆H₄O)3} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tris(2,4-pentanedionato)ruthenium(III) (31378-26-4,31378-27-5,14284-93-6) + (E)-ethyl 4-((2-hydroxybenzylidene)amino)benzoate (3246-76-2) → {Ru(C2H5O2CC6H4NCHC6H4O)3} (111267-20-0)

Guidance literature:

In further solvent(s); byproducts: acetylacetone; addn. of (Ru(CH3COCHCOCH3)3) to soln. of C2H5O2CC6H4NCHC6H4OH in ethyl benzoate; heating to 160°C with stirring for 6 h while a slow stream of N2 is passing through soln.; removing solvent under vac. at 85°C;; dissolving residue in acetone; evapg. filtered soln. under reduced pressure; dissolving crude product in CH2Cl2; chromy. on silica gel column; elution with benzene (rejected) and with benzene/CH2Cl2; crystn. on evapn.; elem. anal.;;

Reference yield:

{Ru(C2H5O2CC6H4NCHC6H4O)3} (111267-20-0) → {Ru(C2H5O2CC6H4NCHC6H4O)3}(1-) (111267-55-1)

Guidance literature:

In acetonitrile; Electrochem. Process; coulometric redn.;; not isolated from soln.; UV, ESR;;

upstream raw materials:

tris(2,4-pentanedionato)ruthenium(III)

(E)-ethyl 4-((2-hydroxybenzylidene)amino)benzoate

Downstream raw materials:

{Ru(C₂H₅O₂CC₆H₄NCHC₆H₄O)3}^(1-)

Refernces