HgBr₂((C₆H₁₁)2PC(S)N(H)C₆H₅)2

Base Information

• Chemical Name: HgBr₂((C₆H₁₁)2PC(S)N(H)C₆H₅)2
• CAS No.: 91885-73-3
• Molecular Formula: C₃₈H₅₆Br₂HgN₂P₂S₂
• Molecular Weight: 1027.35
• Mol file: 91885-73-3.mol

Synonyms:

Chemical Property of HgBr₂((C₆H₁₁)2PC(S)N(H)C₆H₅)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of HgBr₂((C₆H₁₁)2PC(S)N(H)C₆H₅)2

There total 2 articles about HgBr₂((C₆H₁₁)2PC(S)N(H)C₆H₅)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

mercury dibromide + 1-(dicyclohexylphosphino)-N-phenylthioformamide (899-27-4) → HgBr2((C6H11)2PC(S)N(H)C6H5)2 (91885-73-3)

Guidance literature:

In dichloromethane; stirring appropriate amts. (1-(dicyclohexylphosphino))-N-phenylthioformamide) and HgBr2 in CH2Cl2 for 15 min under N2 atm.; ethanol added;

DOI:10.1016/S0020-1693(00)83613-0

Reference yield:

HgBr2(HP(C6H11)2)2 (89954-92-7) + phenyl isothiocyanate (103-72-0) → HgBr2((C6H11)2PC(S)N(H)C6H5)2 (91885-73-3) + HgBr2((C6H11)2PH)((C6H11)2PC(S)N(H)C6H5) (91885-84-6)

Guidance literature:

In dichloromethane; react. equimolar amts. HgBr2(HPcycl2)2 with phenylisothiocyanate in CH2Cl2 under N2;

DOI:10.1016/S0020-1693(00)83613-0

Reference yield:

{mercury(dichloro)bis(dicyclohexylphosphino-N-phenylthioformamide)} (91885-72-2) + HgBr2((C6H11)2PC(S)N(H)C6H5)2 (91885-73-3) → HgClBr((C6H11)2PC(S)N(H)C6H5)2 (91885-75-5)

Guidance literature:

In dichloromethane; mixing equimolar amts. HgCl2((1-(dicyclohexylphosphino))-N-phenylthioformamide)2 and HgBr2((1-(dicyclohexylphosphino)-N-phenylthioformamide)2 in CH2Cl2 under N2; not isolated; identified by NMR;

DOI:10.1016/S0020-1693(00)83613-0

upstream raw materials:

HgBr₂(HP(C₆H₁₁)2)2

phenyl isothiocyanate

1-(dicyclohexylphosphino)-N-phenylthioformamide

Downstream raw materials:

HgClBr((C₆H₁₁)2PC(S)N(H)C₆H₅)2

HgBrI((C₆H₁₁)2PC(S)N(H)C₆H₅)2