Ru(C₅H₅)(P(C₆H₅)3)(C₅H₄N)2⁽¹⁺⁾*Br^(1-)=[Ru(C₅H₅)(P(C₆H₅)3)(C₅H₄N)2]Br

Base Information

• Chemical Name: Ru(C₅H₅)(P(C₆H₅)3)(C₅H₄N)2⁽¹⁺⁾*Br^(1-)=[Ru(C₅H₅)(P(C₆H₅)3)(C₅H₄N)2]Br
• CAS No.: 97286-25-4
• Molecular Formula: Br*C₃₃H₂₈N₂PRu
• Molecular Weight: 664.546
• Mol file: 97286-25-4.mol

Synonyms:

Chemical Property of Ru(C₅H₅)(P(C₆H₅)3)(C₅H₄N)2⁽¹⁺⁾*Br^(1-)=[Ru(C₅H₅)(P(C₆H₅)3)(C₅H₄N)2]Br

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ru(C₅H₅)(P(C₆H₅)3)(C₅H₄N)2⁽¹⁺⁾*Br^(1-)=[Ru(C₅H₅)(P(C₆H₅)3)(C₅H₄N)2]Br

There total 1 articles about Ru(C₅H₅)(P(C₆H₅)3)(C₅H₄N)2⁽¹⁺⁾*Br^(1-)=[Ru(C₅H₅)(P(C₆H₅)3)(C₅H₄N)2]Br which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[2,2]bipyridinyl (366-18-7) + [(η5-cyclopentadienyl)Ru(PPh3)2Br] (32993-06-9) → Ru(C5H5)(P(C6H5)3)(C5H4N)2(1+)*Br(1-)=[Ru(C5H5)(P(C6H5)3)(C5H4N)2]Br (97286-25-4)

Guidance literature:

In ethanol; Bipy added to refluxed soln. (Ru(η5-C5H5)(PPh3)2Br) in ethanol and refluxing continued for 12 h under N2 atm.; volume soln. reduced, diethyl ether added, crystals recrystd. from CH2Cl2/ether mixt., centrifuged, washed with methanol, water, methanol, ether and dried in vacuo; elem. anal.;

DOI:10.1016/S0020-1693(00)87599-4

Reference yield:

Ru(C5H5)(P(C6H5)3)(C5H4N)2(1+)*Br(1-)=[Ru(C5H5)(P(C6H5)3)(C5H4N)2]Br (97286-25-4) + nitrosylchloride (2696-92-6) → (Ru2(NO)2(P(C6H5)3)2(N2C10H8)Cl4Br2)

Guidance literature:

In dichloromethane; to soln. (Ru(η5-C5H5)(PPh3)(Bipy))Br in CH2Cl2 saturated soln. NOClin CH2Cl2 added and mixt. stirred for 30 min under N2 atm.; mixt. concd. under reduced pressure, soln. filtered, n-hexane added, products filtered, washed with petroleum ether (40-60°C) and dried under vac.; elem. anal.;

DOI:10.1016/S0020-1693(00)87600-8

Reference yield:

Ru(C5H5)(P(C6H5)3)(C5H4N)2(1+)*Br(1-)=[Ru(C5H5)(P(C6H5)3)(C5H4N)2]Br (97286-25-4) + nitrosyl bromide (13444-87-6) → (Ru2(NO)2(P(C6H5)3)2(N2C10H8)Br6)

Guidance literature:

In dichloromethane; to soln. (Ru(η5-C5H5)(PPh3)(Bipy))Br in CH2Cl2 saturated soln. NOBrin CH2Cl2 added and mixt. stirred for 30 min under N2 atm.; mixt. concd. under reduced pressure, soln. filtered, n-hexane added, products filtered, washed with petroleum ether (40-60°C) and dried under vac.; elem. anal.;

DOI:10.1016/S0020-1693(00)87600-8

upstream raw materials:

[2,2]bipyridinyl

[(η5-cyclopentadienyl)Ru(PPh3)2Br]