N-[(1E)-ethylidene]ethanamine

Base Information

• Chemical Name: N-[(1E)-ethylidene]ethanamine
• CAS No.: 1190-79-0
• Molecular Formula: C4H9 N
• Molecular Weight: 71.1222
• Mol file: 1190-79-0.mol

Synonyms:Ethylamine,N-ethylidene- (6CI,7CI,8CI); Ethylideneethylamine; N-Ethylethanimine;N-Ethylideneethanamine; N-Ethylideneethylamine

Chemical Property of N-[(1E)-ethylidene]ethanamine

Chemical Property:

• Vapor Pressure: 86.7mmHg at 25°C
• Boiling Point: 82.7°C at 760 mmHg
• Density: 0.71g/cm³

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N-[(1E)-ethylidene]ethanamine

There total 20 articles about N-[(1E)-ethylidene]ethanamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

ethylamine (75-04-7,85404-22-4) → 3-aza-2-pentene (1190-79-0) + acetaldehyde (75-07-0,9002-91-9) + acetonitrile (75-05-8,26809-02-9)

Guidance literature:

With oxygen; In water; at 225 ℃; for 1h; under 750.075 Torr; Time; Catalytic behavior; Mechanism; Flow reactor;

DOI:10.1039/c5cy00577a

Reference yield: 3.6%

N,N-diethyl-2-propynylamine (4079-68-9,125678-52-6) → 1-ethyl-2-methylpyrrole (19983-83-6) + 1,2-propanediene (463-49-0) + 3-aza-2-pentene (1190-79-0)

Guidance literature:

at 450 ℃; under 24 Torr; Product distribution; Mechanism;

DOI:10.1021/jo00071a015

Reference yield:

Bis-(trifluormethyl)-bis-(trifluormethoxy)-sulfuran (63465-11-2) + N,N-diethyl-1,1,1-trimethylsilanamine (996-50-9) → Carbonyl fluoride (353-50-4) + trimethylsilyl fluoride (420-56-4) + 3-aza-2-pentene (1190-79-0) + trifluoro(trifluoromethyl)sulfur(IV) (374-10-7)

Guidance literature:

With NaF; -196 to -78°C, in presence of NaF;

upstream raw materials:

tetraethyl-2-tetrazene

N,N-diethyl-2-propynylamine

diethylamine

diethyl ether

Downstream raw materials:

diethylamine

N-ethyl-N-vinylbenzamide

N-<1-(4-Nitrobenzoyloxy)ethyl>-N-nitrosoethylamin

1-(N-Nitroso-N-ethylamino)ethyl acetate

Refernces

• 1、 Deutscher, Jennifer,Corona, Teresa,Warm, Katrin,Engelmann, Xenia,Sobottka, Sebastian,Braun-Cula, Beatrice,Sarkar, Biprajit,Ray, Kallol. "Water Oxidation Reaction Mediated by an Octanuclear Iron-Oxo Cluster". supporting information. p. 4925 - 4929. Retrieved 2018/05/30.
• 2、 McClain, K. Randall,O'Donohue, Christopher,Koley, Arijit,Bonsu, Richard O.,Abboud, Khalil A.,Revelli, Joseph C.,Anderson, Timothy J.,McElwee-White, Lisa. "Tungsten nitrido complexes as precursors for low temperature chemical vapor deposition of WNxCy films as diffusion barriers for Cu metallization". supporting information. p. 1650 - 1662. Retrieved 2014/02/14.