Cyclododecane, phenyl-

Base Information

• Chemical Name: Cyclododecane, phenyl-
• CAS No.: 15971-88-7
• Molecular Formula: C18H28
• Molecular Weight: 244.42
• Mol file: 15971-88-7.mol

Synonyms:Phenyl-cyclododecan;Cyclododecylbenzene;Cyclododecylbenzol;Cyclododecane, phenyl-;

Chemical Property of Cyclododecane, phenyl-

Chemical Property:

• Melting Point: 34.5 °C
• Boiling Point: 155-156 °C(Press: 2 Torr)
• PSA: 0.00000
• Density: 0.9410 g/cm3(Temp: 45 °C)
• LogP: 6.07490

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Cyclododecane, phenyl-

There total 7 articles about Cyclododecane, phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

cyclododecene (1501-82-2) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → phenylcyclododecane (15971-88-7)

Guidance literature:

With Et₃NH[Al₂Cl₇]; at 40 ℃; for 6h; Temperature; Inert atmosphere;

DOI:10.1134/S107036321911001X

Reference yield: 97.0%

methanesulfonyl-cyclododecane + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → phenylcyclododecane (15971-88-7)

Guidance literature:

With copper(II) bis(trifluoromethanesulfonate); In 1,2-dichloro-ethane; at 80 ℃; for 4h;

DOI:10.1016/S0040-4020(00)01005-X

Reference yield: 50.0%

cyclododecane (294-62-2) + acrylonitrile (107-13-1,25014-41-9) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → phenylcyclododecane (15971-88-7) + 3-cyclododecylpropanenitrile (69300-14-7)

Guidance literature:

With benzophenone; for 15h; Irradiation;

DOI:10.1021/jo010400k

upstream raw materials:

cyclododecene

benzene

cis-cyclododecene

cyclododecane

Downstream raw materials:

Cyclohexyl-cyclododecan

Refernces

• 1、 Toriyama, Fumihiko,Cornella, Josep,Wimmer, Laurin,Chen, Tie-Gen,Dixon, Darryl D.,Creech, Gardner,Baran, Phil S.. "Redox-Active Esters in Fe-Catalyzed C-C Coupling". . p. 11132 - 11135. Retrieved 2016/10/12.
• 2、 Cardarelli,Fagnoni,Mella,Albini. "Hydrocarbon activation. Synthesis of β-cycloalkyl (Di)nitriles through photosensitized conjugate radical addition". . p. 7320 - 7327. Retrieved 2007/10/03.