1,3-Propanediol, diformate

Base Information

• Chemical Name: 1,3-Propanediol, diformate
• CAS No.: 1727-40-8
• Molecular Formula: C5H8O4
• Molecular Weight: 132.116
• Mol file: 1727-40-8.mol

Synonyms:

Chemical Property of 1,3-Propanediol, diformate

Chemical Property:

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,3-Propanediol, diformate

There total 3 articles about 1,3-Propanediol, diformate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

paraformaldehyde + formic acid (64-18-6) + ethene (74-85-1) → 1,3-dioxane (505-22-6) + 1,1,1,-tris(hydroxymethyl)ethane triformate (120570-78-7) + 1,3-propanediol diformate (1727-40-8)

Guidance literature:

ytterbium(III) triflate; In water; at 70 - 130 ℃; for 16h; under 51755.2 Torr; Product distribution / selectivity;

Reference yield:

formaldehyd (50-00-0,30525-89-4,61233-19-0) + formic acid (64-18-6) + ethene (74-85-1) → 1,3-dioxane (505-22-6) + 1,1,1,-tris(hydroxymethyl)ethane triformate (120570-78-7) + 1,3-propanediol diformate (1727-40-8)

Guidance literature:

ytterbium(III) triflate; In water; at 130 ℃; for 16h; under 51755.2 Torr; Product distribution / selectivity;

Reference yield:

glycerol trimethanoate (32765-69-8) → 1,2-propanediol diformate (53818-14-7) + 1,3-propanediol diformate (1727-40-8)

Guidance literature:

With di-tert-butyl peroxide; at 140 ℃; for 3h; conversion, concentration of products;

upstream raw materials:

glycerol trimethanoate

formaldehyd

formic acid

ethene

Downstream raw materials:

trimethyleneglycol

Refernces

• 1、 Nurberdiev, R.,Khekimov, Yu. K.,Rol'nik, L. Z.,Zlot-skii, S. S.,Rakhmankulov, D. L.. "HOMOLYTIC REACTIONS OF FORMATES OF ALCOHOLS AND GLYCOLS". . p. 1411 - 1413. Retrieved 2007/10/02.