Dodecylmagnesium chloride

Base Information

• Chemical Name: Dodecylmagnesium chloride
• CAS No.: 18996-28-6
• Molecular Formula: C12H25ClMg
• Molecular Weight: 229.089
• Mol file: 18996-28-6.mol

Synonyms:n-dodecylmagnesium chloride;n-dodecyl magnesium chloride;Dodecylmagnesiumchlorid;

Chemical Property of Dodecylmagnesium chloride

Chemical Property:

• PSA: 0.00000
• LogP: 5.56440

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Dodecylmagnesium chloride

There total 1 articles about Dodecylmagnesium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

diethyl ether (60-29-7,927820-24-4) + 1-chlorododecane (112-52-7) → dodecane (112-40-3) + 1-dodecene (112-41-4,25067-08-7,62132-67-6) + tetracosane (646-31-1) + dodecylmagnesium chloride (18996-28-6)

Guidance literature:

Reference yield: 91.0%

ethyl 2-iodobenzoate (1829-28-3) + dodecylmagnesium chloride (18996-28-6) → ethyl 2-dodecylbenzoate

Guidance literature:

dodecylmagnesium chloride; With zinc(II) chloride; In tetrahydrofuran;

ethyl 2-iodobenzoate; With dichloro bis(acetonitrile) palladium(II); diethyl bicyclo[2.2.1]hept-2,5-diene-2,3-dicarboxylate; In tetrahydrofuran; at 60 ℃; for 2h; Inert atmosphere;

DOI:10.1002/adsc.200800118

Reference yield: 75.0%

dodecylmagnesium chloride (18996-28-6) → 1-fluorododecane (334-68-9)

Guidance literature:

With 1-fluoro-2,4,6-trimethylpyridinium trifluoromethanesulfonate; In diethyl ether; at 0 ℃; for 0.5h;

DOI:10.15227/orgsyn.069.0129

upstream raw materials:

diethyl ether

1-chlorododecane

Downstream raw materials:

formaldehyde ditridecylacetal

tridecan-1-ol

n-dodecylboronic acid

tetradecan-2-ol