1-(2-Furyl)ethylene glycol

Base Information

• Chemical Name: 1-(2-Furyl)ethylene glycol
• CAS No.: 19377-75-4
• Molecular Formula: C6H8O3
• Molecular Weight: 128.128
• Hs Code.: 2932190090
• Mol file: 19377-75-4.mol

Synonyms:1-<2>-Furyl-ethan-1,2-diol;1-(2-furanyl)-1,2-ethanediol;1-(2-furyl)-1,2-ethanediol;1-(2-Furyl)ethylene glycol;furan glycol;furan-2-yl-ethane-1,2-diol;2-(1,2-Dihydroxyethyl)-furan;1-(2-Furyl)ethane-1,2-diol;1,2-Ethanediol,1-(2-furanyl);

Chemical Property of 1-(2-Furyl)ethylene glycol

Chemical Property:

• Boiling Point: 83-85 °C(Press: 0.01 Torr)
• PKA: 13.28±0.20(Predicted)
• PSA: 53.60000
• Density: 1.271±0.06 g/cm3(Predicted)
• LogP: 0.30530

Purity/Quality:

1-(2-furanyl)-1,2-Ethanediol 97.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-(2-Furyl)ethylene glycol

There total 13 articles about 1-(2-Furyl)ethylene glycol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

(furan-2-yl)ethylene (1487-18-9) → 1-(furan-2-yl)ethane-1,2-diol (19377-75-4)

Guidance literature:

With osmium(VIII) oxide; N-methyl-2-indolinone; In tetrahydrofuran; at 20 ℃; for 48h;

DOI:10.1055/s-2000-7099

Reference yield: 91.0%

2-furyloxirane (2745-17-7) → 1-(furan-2-yl)ethane-1,2-diol (19377-75-4)

Guidance literature:

With boron trifluoride diethyl etherate; In dichloromethane; at -64 ℃;

DOI:10.1080/00397919108021571

Reference yield: 59.0%

Wilkinson's catalyst (14694-95-2) + D-manno-2-heptulose (470-46-2,470-47-3,562-61-8,562-62-9,665-25-8,20197-43-7,36660-76-1,60426-75-7,60426-76-8,60426-77-9,60426-78-0,60426-79-1,3615-44-9) → chlorocarbonylbis(triphenylphosphine)rhodium(I) (15318-33-9,16353-77-8,13938-94-8) + 1-(furan-2-yl)ethane-1,2-diol (19377-75-4) + 2,7-anhydro-manno-2-heptulopyranose (7739-21-1,5397-35-3)

Guidance literature:

In further solvent(s); argon-filled glovebox, durene, bibenzyl, 130°C, 23h; product detd. by GC and IR;

DOI:10.1021/om00113a029

upstream raw materials:

2-furyloxirane

(furan-2-yl)ethylene

2-(1-hydroxy-2-chloroethyl)-furan

Wilkinson's catalyst

Downstream raw materials:

6-hydroxy-2-hydroxymethyl-6H-pyran-3-one

2-furan-2-yl-quinoxaline

1,6-anhydro-2,3-dideoxy-β-threo-hex-2-enopyranose

(-)-(1S,5S)-Isolevoglucosenone

Refernces

• 1、 Chatterjee, Maya,Ishizaka, Takayuki,Chatterjee, Abhijit,Kawanami, Hajime. "Dehydrogenation of 5-hydroxymethylfurfural to diformylfuran in compressed carbon dioxide: An oxidant free approach". . p. 1315 - 1326. Retrieved 2017/08/15.
• 2、 Yousuf, Syed Khalid,Taneja, Subhash Chandra,Mukherjee, Debaraj. "Multicomponent cascade transformation of d -glucal to furan-appended triazole glycoconjugates". supporting information; experimental part. p. 3097 - 3100. Retrieved 2010/07/17.