2-(Oxiran-2-yl)furan

Base Information

• Chemical Name: 2-(Oxiran-2-yl)furan
• CAS No.: 2745-17-7
• Molecular Formula: C6H6O2
• Molecular Weight: 110.112
• DSSTox Substance ID: DTXSID10415848
• Nikkaji Number: J541.932H
• Mol file: 2745-17-7.mol

Synonyms:2-(oxiran-2-yl)furan;2745-17-7;2-Furyloxirane;2-oxiran-2-ylfuran;SCHEMBL434835;DTXSID10415848;AKOS000142282;AKOS022221802;EN300-36263

Chemical Property of 2-(Oxiran-2-yl)furan

Chemical Property:

• Vapor Pressure: 2.71mmHg at 25°C
• XLogP3: 0.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 110.036779430
• Heavy Atom Count: 8
• Complexity: 92.5

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1C(O1)C2=CC=CO2

Technology Process of 2-(Oxiran-2-yl)furan

There total 3 articles about 2-(Oxiran-2-yl)furan which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

furfural (98-01-1) + trimethylsulphonium bromide (3084-53-5) → 2-furyloxirane (2745-17-7)

Guidance literature:

With potassium hydroxide; In neat (no solvent); Mechanism; var. other bases, effect of water;

Reference yield: 93.0%

furfural (98-01-1) + trimethylsulphonium bromide (3084-53-5) → 2-furyloxirane (2745-17-7) + dimethylsulfide (75-18-3)

Guidance literature:

With potassium hydroxide; In acetonitrile; at 40 ℃; for 0.833333h;

DOI:10.1016/S0040-4020(01)85887-7

Reference yield:

furfural (98-01-1) + trimethylsulphonium iodide (2181-42-2) + acetonitrile (75-05-8,26809-02-9) → (2-furyl)methyl alcohol (98-00-0,25212-86-6,93793-62-5) + 2-furanoic acid (88-14-2) + 2-furyloxirane (2745-17-7) + (E)-3-(2-furyl)acrylonitrile (6125-63-9,7187-01-1)

Guidance literature:

With potassium hydroxide; In water; at 60 ℃; Product distribution; Mechanism; var. of base, amount of H₂O, rate of stirring, condition of KOH, solvent, without Me₃SI;

DOI:10.1039/c39940002309

upstream raw materials:

furfural

trimethylsulphonium bromide

trimethylsulphonium iodide

acetonitrile

Downstream raw materials:

2-(2-furyl)-2-ethoxyethanol

(furan-2-yl)ethylene

1-(2-furyl)ethanol

2-(furan-2-yl)ethanol

Refernces

• 1、 Borredon, M. E.,Sinisterra, J. V.,Delmas, M.,Gaset, A.. "EPOXYDATION EN MILIEU HETEROGENE SOLIDE-LIQUIDE FAIBLEMENT HYDRATE I : ETUDE DES INTERACTIONS MOLECULAIRES : SEL DE SULFONIUM-BASE". . p. 4141 - 4146. Retrieved 1987.
• 2、 Brochet,Syssa,Mouloungui,Delmas,Gaset. "Homologation of furfural and derivatives to furylacetaldehydes". . p. 1735 - 1741. Retrieved 2007/10/02.
• 3、 Borredon, M. E.,Mouloungui, Z.,Delmas, M.,Gaset, A.. "RELATIONS RELATIVITE/STRUCTURE DANS LES REACTIONS EFFECTUEES EN MILIEU HETEROGENE SOLIDE/LIQUIDE FAIBLEMENT HYDRATE". . p. 479 - 486. Retrieved 2007/10/02.