13-OXOOCTADECANOIC ACID

Base Information

• Chemical Name: 13-OXOOCTADECANOIC ACID
• CAS No.: 2389-06-2
• Molecular Formula: C18H34O3
• Molecular Weight: 298.46100
• Mol file: 2389-06-2.mol

Synonyms:13-Oxo-stearinsaeure;13-oxostearic acid;13-Oxo-octadecansaeure;13-oxo-octadecanoic acid;13-Oxostearinsaeure;

Chemical Property of 13-OXOOCTADECANOIC ACID

Chemical Property:

• Melting Point: 82 °C
• PSA: 54.37000
• LogP: 5.51150

Purity/Quality:

95% ^*data from raw suppliers

13-OXOOCTADECANOIC ACID 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 13-OXOOCTADECANOIC ACID

There total 10 articles about 13-OXOOCTADECANOIC ACID which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

methyl 13-oxooctadecanoate (2380-28-1) → 13-oxooctadecanoic acid (2389-06-2)

Guidance literature:

With potassium hydroxide; In ethanol; at 20 ℃;

DOI:10.1016/j.chemphyslip.2014.07.007

Reference yield:

13-oxo-9Z,11E-octadecadienoic acid (54739-30-9) → 13-oxooctadecanoic acid (2389-06-2)

Guidance literature:

With hydrogen; palladium on activated charcoal; In methanol; Ambient temperature;

DOI:10.1271/bbb.63.489

Reference yield:

(R,S)-coriolic acid (10219-69-9,29623-28-7,29899-88-5,32819-31-1,73804-64-5,81445-95-6,114297-05-1,114818-04-1,114818-05-2,127911-29-9,128821-19-2,5204-88-6,149341-86-6,18104-45-5) → 13-oxooctadecanoic acid (2389-06-2)

Guidance literature:

Multi-step reaction with 2 steps

1: 4.3 mg / activated MnO₂ / CHCl₃ / 4 h / Ambient temperature

2: 1.9 mg / H₂ / Pd/C / methanol / Ambient temperature

With manganese(IV) oxide; hydrogen; palladium on activated charcoal; In methanol; chloroform;

DOI:10.1271/bbb.63.489

upstream raw materials:

methyl 3-oxooctanoate

ethyl 11-iodoundecanoate

2-butyl-1,3-cyclotetradecanedione

13-oxo-9Z,11E-octadecadienoic acid

Downstream raw materials:

Methyl-13-hydroxystearat

Refernces

• 1、 Afri, Michal,Alexenberg, Carmit,Aped, Pinchas,Bodner, Efrat,Cohen, Sarit,Ejgenburg, Michal,Eliyahu, Shlomi,Gilinsky-Sharon, Pessia,Harel, Yifat,Naqqash, Miriam E.,Porat, Hani,Ranz, Ayala,Frimer, Aryeh A.. "NMR-based molecular ruler for determining the depth of intercalants within the lipid bilayer. Part III: Studies on keto esters and acids". . p. 105 - 118. Retrieved 2015/02/19.
• 2、 Watanebe, Jun,Kawabata, Jun,Kasai, Takanori. "9-Oxooctadeca-10,12-dienoic acids as Acetyl-CoA carboxylase inhibitors from red pepper (Capsicum annuum L.)". . p. 489 - 493. Retrieved 2007/10/03.