2-Anthracenesulfonic acid, 1-amino-9,10-dihydro-9,10-dioxo-, monosodium salt

Base Information

• Chemical Name: 2-Anthracenesulfonic acid, 1-amino-9,10-dihydro-9,10-dioxo-, monosodium salt
• CAS No.: 24429-49-0
• Molecular Formula: C14H9NO5S.Na
• Molecular Weight: 325.277
• Mol file: 24429-49-0.mol

Synonyms:Na-1-Amino-anthrachinon-2-sulfonat;1-Amino-9,10-dioxo-9,10-dihydro-anthracen-2-sulfonsaeure, Natrium-Salz;sodium 1-aminoanthraquinone-2-sulfonate;1-amino-9,10-dioxo-9,10-dihydro-anthracene-2-sulfonic acid , sodium-salt;

Chemical Property of 2-Anthracenesulfonic acid, 1-amino-9,10-dihydro-9,10-dioxo-, monosodium salt

Chemical Property:

• PSA: 125.74000
• LogP: 2.61030

Purity/Quality:

98.5% ^*data from raw suppliers

Sodium1-amino-9,10-dioxo-9,10-dihydroanthracene-2-sulfonate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-Anthracenesulfonic acid, 1-amino-9,10-dihydro-9,10-dioxo-, monosodium salt

There total 5 articles about 2-Anthracenesulfonic acid, 1-amino-9,10-dihydro-9,10-dioxo-, monosodium salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

1-amino-9,10-anthracenedione (82-45-1) → sodium 1-amino-9,10-dioxo-9,10-dihydroanthracene-2-sulfonate (24429-49-0)

Guidance literature:

With sodium sulfite; In pyridine; water; at 22 ℃; for 6h; Product distribution; Irradiation; yield with different additives;

DOI:10.1039/P29800001544

Reference yield: 71.0%

sodium 1-amino-4-bromoanthraquinone-2-sulfonate (6258-06-6) → sodium 1-amino-9,10-dioxo-9,10-dihydroanthracene-2-sulfonate (24429-49-0)

Guidance literature:

With iron; sodium carbonate; acetic acid; for 6h; Heating;

DOI:10.1016/j.ejmech.2005.07.007

Reference yield: 8.0%

sodium 1-amino-4-bromoanthraquinone-2-sulfonate (6258-06-6) → sodium 1-amino-9,10-dioxo-9,10-dihydroanthracene-2-sulfonate (24429-49-0) + sodium 1-amino-4-hydroxy-9,10-dioxo-9,10-dihydroanthracene-2-sulfonate (25492-62-0) + disodium 4,4'-diamino-1,1'-bianthraquinonyl-3,3'-disulfonate (6022-22-6)

Guidance literature:

With copper(II) sulfate; In 1,4-dioxane; at 25 ℃; Product distribution; Mechanism; Electrochemical reduction with/without presence of aniline; atmosphere of air or argon.;

upstream raw materials:

sodium 1-amino-4-bromoanthraquinone-2-sulfonate

1-amino-9,10-anthracenedione

1-amino-2-mercapto-9,10-antraquinone sodium salt

Downstream raw materials:

sodium 1-amino-4-bromoanthraquinone-2-sulfonate

1-amino-2, 4-dibromoanthraquinone

1-amino-9,10-anthracenedione

Refernces

• 1、 Gl?nzel, Markus,Bültmann, Ralph,Starke, Klaus,Frahm, August W.. "Structure-activity relationships of novel P2-receptor antagonists structurally related to Reactive Blue 2". . p. 1262 - 1276. Retrieved 2007/10/03.
• 2、 Hamilton, Kenneth,Hunter, John A.,Preston, Peter N.,Morley, John O.. "Photochemical Substitution of Amino- and Hydroxy-anthraquinones". . p. 1544 - 1548. Retrieved 2007/10/02.