3-Chloro-1,1-diphenylpropene

Base Information

• Chemical Name: 3-Chloro-1,1-diphenylpropene
• CAS No.: 24626-27-5
• Molecular Formula: C15H13Cl
• Molecular Weight: 228.721
• DSSTox Substance ID: DTXSID00512395
• Nikkaji Number: J2.401.608K
• Mol file: 24626-27-5.mol

Synonyms:24626-27-5;3-CHLORO-1,1-DIPHENYLPROPENE;(3-chloroprop-1-ene-1,1-diyl)dibenzene;(3-chloro-1-phenylprop-1-enyl)benzene;3,3-diphenyl-2-propenyl chloride;3,3-Diphenylallyl Chloride;SCHEMBL7242171;3-chloro-1,1-diphenyl-propene;DTXSID00512395;MTOVXZPDHLKNAO-UHFFFAOYSA-N;1,1-diphenyl-3-chloro-1-propene;1,1'-(3-Chloroprop-1-ene-1,1-diyl)dibenzene;(3-CHLORO-1-PHENYLPROP-1-EN-1-YL)BENZENE

Chemical Property of 3-Chloro-1,1-diphenylpropene

Chemical Property:

• Boiling Point: 347.4oC at 760 mmHg
• Flash Point: 156.6oC
• PSA: 0.00000
• Density: 1.098g/cm3
• LogP: 4.35710
• XLogP3: 4.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 228.0705781
• Heavy Atom Count: 16
• Complexity: 200

Purity/Quality:

98.5% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C(=CCCl)C2=CC=CC=C2

Technology Process of 3-Chloro-1,1-diphenylpropene

There total 10 articles about 3-Chloro-1,1-diphenylpropene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

3,3-diphenylprop-2-en-1-ol (4801-14-3) → 3,3-diphenylallyl chloride (24626-27-5)

Guidance literature:

With triethylamine; In dichloromethane; at 20 ℃;

DOI:10.1016/S0968-0896(01)00436-9

Reference yield: 81.0%

→ 3,3-diphenylallyl chloride (24626-27-5)

Guidance literature:

Reference yield:

ethyl 3-chloropropanoate (623-71-2) + phenylmagnesium bromide → 3-chloropropiophenone (936-59-4) + 3,3-diphenylallyl chloride (24626-27-5)

Guidance literature:

With diethyl ether; Destillation des nach Hydrolyse erhaltenen Reaktionsprodukts unter vermindertem Druck;

DOI:10.1039/jr9360000401

upstream raw materials:

diethyl ether

ethyl 3-chloropropanoate

1,1-diphenylprop-2-en-1-ol

3,3-diphenylprop-2-en-1-ol

Downstream raw materials:

methyl (+/-)-3-(3,3-diphenyl-2-propenyl)-4-oxo-1-piperidinecarboxylate

1,6-dioxo-6a-(3,3-diphenyl-2-propenyl)-2,3,3a,4,5,6,6a,7a-octahydropyrido<3,2,1-jk>carbazole

1,1-diphenyl-3-(trimethylsilyl)-1-propene

(1S,2S,5S)-2-(3,3-Diphenyl-allyl)-3-oxo-bicyclo[3.3.1]nonane-1-carbonitrile

Refernces

• 1、 Pape, Felix,Brechmann, Lea T.,Teichert, Johannes F.. "Catalytic Generation and Chemoselective Transfer of Nucleophilic Hydrides from Dihydrogen". supporting information. p. 985 - 988. Retrieved 2019/01/04.
• 2、 -. "Physical properties and excellent thermal stability microporous polyolefin film temp.". . . Retrieved 2007/10/15.