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Cas Database

Name	Sodium benzenolate	EINECS	205-347-3
CAS No.	139-02-6	Density	0,898 g/cm3
PSA	23.06000	LogP	1.83040
Solubility	Very soluble in water, soluble in alcoholSoluble in water, acetone and alcohol.	Melting Point	>300℃
Formula	C6H6 O . Na	Boiling Point	181.8 °C at 760 mmHg
Molecular Weight	116.095	Flash Point	28°C
Transport Information	N/A	Appearance	white like or light brown crystalline powder
Safety	Poison by subcutaneous route. A corrosive irritant to skin, eyes, and mucous membranes. When heated to decomposition it emits toxic fumes of Na₂O. See also PHENOL and SODIUM HYDROXIDE.	Risk Codes	34
Molecular Structure		Hazard Symbols	Strong irritant to skin and tissue.
Synonyms	Phenol,sodium salt (8CI,9CI); Sodium phenoxide (6CI); Phenol sodium; Sodium carbolate;Sodium phenate; Sodium phenolate; Sodium phenylate	Article Data	96

Sodium benzenolate Synthetic route

: 102-09-0
bis(phenyl) carbonate

A: 139-02-6
sodium phenoxide

B: 81256-74-8
sodium salicylat

Conditions

Conditions	Yield
With water; sodium hydroxide In dimethyl sulfoxide at 25℃; Kinetics;	A 100% B n/a

: 108-95-2
phenol

: 139-02-6
sodium phenoxide

Conditions

Conditions	Yield
With sodium hydroxide In methanol; water	98.9%
With sodium In 1,4-dioxane for 4h; Heating;	92%
With methanol; sodium

: 1121-70-6
sodium 4-methylphenoxide

poly(styrene p-tolyliodonium) hydrogensulfate: poly(styrene p-tolyliodonium) hydrogensulfate

: 139-02-6
sodium phenoxide

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 100℃; for 24h;	65%

: 122-99-6
2-Phenoxyethanol

A: 139-02-6
sodium phenoxide

B: 3598-16-1
2-phenoxyacetic acid sodium salt

Conditions

Conditions	Yield
With oxygen; bismuth(III) nitrate; palladium on activated charcoal In sodium hydroxide at 90℃; for 6h; Product distribution; also with coactivator and other activators, various times, reaction with other 2-phenoxyethanols;	A n/a B 53%

: 67-56-1
methanol

: 10113-28-7
dimethyl phenyl phosphate

: 124-41-4
sodium methylate

A: 512-56-1
trimethyl phosphite

B: 139-02-6
sodium phenoxide

Conditions

Conditions	Yield
at 0℃; Rate constant;
at 19℃; Rate constant;
at 10℃; Rate constant;

: 60-29-7
diethyl ether

: 64-17-5
ethanol

: 13400-05-0
trichloro-methanesulfenic acid phenyl ester

: 141-52-6
sodium ethanolate

A: 13029-05-5
trichloro-methanesulfenic acid ethyl ester

B: 139-02-6
sodium phenoxide

...Expand

: 64-17-5
ethanol

: 1247-19-4
diphenyldiphenoxysilane

: furan-2,3,5(4H)-trione pyridine (1:1)

A: 512-63-0
1,1,3,3,5,5-hexaphenylcyclotrisiloxane

B: 139-02-6
sodium phenoxide

: 339199-98-3
1,3,5-trinitro-2,4,6-triphenoxy-benzene

: 141-52-6
sodium ethanolate

A: 68959-41-1
1,3,5-triethoxy-2,4,6-trinitrobenzene

B: 139-02-6
sodium phenoxide

: 110-54-3
hexane

: 676-54-0
ethyl sodium

: 100-66-3
methoxybenzene

: 139-02-6
sodium phenoxide

: 1247-19-4
diphenyldiphenoxysilane

: furan-2,3,5(4H)-trione pyridine (1:1)

: 67-64-1
acetone

A: 512-63-0
1,1,3,3,5,5-hexaphenylcyclotrisiloxane

B: 139-02-6
sodium phenoxide

Sodium benzenolate Chemical Properties

Synonyms: PHENOL,sodiumsalt;PHENOL,sodiumsalt(solid);PHENOLatesodium;PHENOLsodium;PHENOLsodiumsalt;sodiumcarbolate;sodiumPHENOLate,solid;SODIUM PHENATE
SODIUM PHENOXIDE is the chemical compound with the formula C₆H₅NaO.Its molar mass is 116.09.
density:0,898 g/cm³
Flash point:28°C
storage temp.:below 5° C
Sensitive:Hygroscopic

Sodium benzenolate Toxicity Data With Reference

1.		scu-mus LDLo:350 mg/kg		AEXPBL Archiv fuer Experimentelle Pathologie und Pharmakologie. 52 (1905),220.
2.		scu-frg LDLo:100 mg/kg		AEXPBL Archiv fuer Experimentelle Pathologie und Pharmakologie. 52 (1905),220.

Sodium benzenolate Consensus Reports

Sodium PHENOXIDE's reported in EPA TSCA Inventory.

Sodium benzenolate Safety Profile

Poison by subcutaneous route. A corrosive irritant to skin, eyes, and mucous membranes. When heated to decomposition it emits toxic fumes of Na₂O. See also PHENOL and SODIUM HYDROXIDE.

Sodium benzenolate Standards and Recommendations

DOT Classification: 8; Label: Corrosive

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