The reaction typically starts with the oxidation of the β-aminoacrylamide by PhIO. This oxidation process may lead to the formation of an intermediate compound. The key step in the reaction involves the intramolecular cyclization of the intermediate. The β-amino group and acrylamide group react within the same molecule, leading to the formation of isoxazoles and 2H-azirines.
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N-(4-CHLOROPHENYL)-3,5-DIMETHYL-4-ISOXAZOLECARBOXAMIDE
(1Z,3E)-1-chloro-1,4-di(4-methoxyphenyl)buta-1,3-diene
((Z)-41-(2,2-dichlorovinyloxy)but-2-enyloxy)(tert-butyl)diphenylsilane
(R,E)-3-benzylamino-5-phenyl-4-penten-1-ol
perfluoro-(3-methylbuta-1,2-diene)
Pyrrolidine, 1-[1-methyl-1-(4-nitrophenyl)ethyl]-
1-phenylhept-2-ynyl pivalate
()-2-amino-4-methylvaleramide
ethynyl(phenyl)carbamic acid tert-butyl ester
7-methoxy-1-tosyl-2,3-dihydro-1H-benzo[f]indole
3-Bromo-4-thiocyanatoaniline
Ceric ammonium nitrate
trans-4-fluorophenylbis(triphenylphosphine)platinum thiophenoxide
5-methylcyclohex-2-enyl chloride
3-benzyl-3H-benzo[4,5]imidazo[2,1-i]purine
Benzenamine, 2,4-dichloro-N-sulfinyl-
Naphthalene, 1-(2,2-dimethylpropyl)-
methyl 2-methyl-3-triphenylsilylpropionate
2-bromo-4-phenyl-4-butanolide
2-Propynamide, N-methoxy-N-methyl-3-phenyl-
2,5-Dihydro-2,5-dimethoxyfuran
2-Propanone, 1-(4-benzoylphenyl)-
3(2H)-Furanone, 5-(4-methoxyphenyl)-2,2-dimethyl-
10H-Phenoxazin-3-aMine
4
Ammonium chloride
(RS:3RS)-2-chloro-3-methoxy-3-phenyl-propionic acid
5-Decen-2-one, 4-phenyl-, (5E)-
(2S,3R)-2-[3-(4-Benzyloxy-phenyl)-propyl]-3-[(S)-2-(4-iodo-phenyl)-1-methoxycarbonyl-ethylcarbamoyl]-5-methyl-hexanoic acid tert-butyl ester
2-<2-(tert-butyldiphenylsiloxy)ethoxy>ethyl 2,3-epoxypent-4-enyl ether
C14H12O(18)O
2-(4,5-DIHYDRO-4,4-DIMETHYLOXAZOL-2-YL)BENZENAMINE
4(3H)-Quinazolinone, 3-(2-fluorophenyl)-
[Cr(5,10,15,20-tetraphenylporphinate)Cl(1-methylimidazole)]
Toluene
cis-2-((phenylthio)methyl)-5-methylcyclohexanone
Oxirane, 2-(4-chlorophenyl)-3-phenyl-, (2S,3S)-
tert-butyl 2-((2-methyl-3-oxo-5-phenylcyclopent-1-enyl)methyl)-1H-pyrrole-1-carboxylate
(E)-Pent-3-enoic acid ((E)-but-2-enyl)amide
Benzenemethanamine, a-butyl-, (R)-
1-(4-chlorophenyl)-2-[N-(1,3-dioxoisoindolin-2-yl)acetamido]ethyl 2,2,2-trifluoroacetate
(E)-1-methoxy-4-(penta-1,4-diene-1-yl)benzene
1-Propanone, 2-(1-ethoxyethoxy)-1-phenyl-
3-Cyclobutene-1,2-dione, 3,4-bis(4-nitrophenoxy)-
5-butyl-3-(4-chlorophenyl)isoxazole
FORMANILIDE
4-(cyclohexylmethyl)-4-vinyl-1,2,3-oxathiazinane 2,2-dioxide
1-methyl-4-[(2-nitroethyl)sulfanyl]benzene
(S)-3-hydroxy-1-(4’-methoxylphenyl)-3-phenylpropan-1-one
(2S)-2-[benzyl(2-{benzyl[(1S)-2-hydroxy-1-phenylethyl]amino}ethyl)amino]-2-phenylethan-1-ol
4-bromo-5-phenylpent-4-en-1-ol
1-Cycloundecene-1-carboxylic acid, methyl ester, (E)-
