The reaction involves the nucleophilic substitution of the azide ion on the sulfonium salt. This can be carried out under specific reaction conditions depending on the choice of precursors. For example, one common method involves the use of an alkyl or aryl sulfonium salt, such as a sulfonium chloride or sulfonium iodide, and treating it with an azide source like sodium azide (NaN3).
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triphenylsulfonium azide
Dichloromethane
Silver azide
(1,1-difluoroethyl)triethylsilane
5-phenyl-1,4-di(p-toluenesulfonyl)-1,2,3,4-tetrahydropyrazine
2-phenylsulfanyl-N,N-diphenyl-2-phenylacetamide
2-[2-(4-methoxyphenyl)-2,3-dihydro-1,5-benzothiazepin-4-yl]phenol
3-CHLORO-4-FLUOROTHIOBENZAMIDE
C26H18Se
N-((1S,2S,5R)-2-isopropyl-5-methylcyclohexyl)aniline
ethyl 2,2-difluoro-3-hydroxy-5-phenylpentanoate
1H-1,5-Benzodiazepine, 6,8-dichloro-2,3-dihydro-2-methyl-2,4-bis(4-nitrophenyl)-
N-(2-(furan-2-yl)butan-2-yl)-P,P-diphenylphosphinic amide
2-[(E)-3-(4-hydroxyphenyl)-2-methyl-1-(pyrrolidinyl)-prop-2-en-1-ylidene]-5,5-dimethyl-cyclohexane-1,3-dione
3-sulfanylheptyl acetate
6-methoxy-2-methyl-3,4-dihydronaphthalen-1(2H)-one
4-[1-(2-methylphenyl)-benzylidene]-1-(4-methylphenylsulfonyl)-piperidine
o-Phenylenediamine
Cyclopropanecarboxylic acid, 1-amino-2-ethenyl-, (1R,2S)- (9CI)
(3,3-Difluoro-propenylidene)-cyclohexane
2-Propanone, 1-bromo-3-(4-chlorophenoxy)-
2-ethoxy-1-indanone
1H-Benzimidazole,2-(methylsulfinyl)-,(R)-(9CI)
(RS)-N-benzyl 2-(pyridin-2-yl)acetamide
3a-butyl-9b-hydroxy-5-methyl-1-phenyl-2-thioxo-1,2,3,3a,5,9b-hexahydroimidazo[4,5-c]quinolin-4-one
Benzenamine, 2-(1,1-dimethyl-2-propenyl)-
(R)-3-amino-3-phenylprop-1-yne
phthalimide
triphenylphosphine
N-<(1R,2R,3S,4S)-2-hydroxy-1,7,7-trimethylbicyclo<2.2.1>heptan-3-yl>-2<(S)-1-benzyloxycarbonyl>prolinamide
DL-Ornithine hydrochloride
6-Hydroxy-5-nitroquinoline
2-fluoro-5-phenyl-3-trifluoromethylthiophene
2,4-diphenyltetrahydrofuran
5,5-bis(phenylsulfonyl)-2-methyl-2-penten-1-ol
3-Bromobenzyl-acetohydroxamic acid
((E)-1-Methyl-propenyl)-triphenyl-silane
2-<(4-fluorobutyl)oxy>pyridine
1,2-DIHYDRO-2-TRIFLUOROMETHYL-4H-THIENO-[2,3-C]-CHROMENE-4-ONE
Disiloxane, 1,3-diphenyl-
Cyclododecanone, 2-iodo-
2-(α-bromobenzylidene)adamantane
Benzenesulfonamide, 4-chloro-N-[2-phenyl-2-(phenylamino)ethyl]-
3,4-Bis<(1-acetoxycyclohexyl)carbonyl>furoxan
2,6-di-tert-amylnaphthalene
[(S)-1-Dimethoxymethyl-3-((R)-1-phenyl-ethylcarbamoyl)-propyl]-carbamic acid tert-butyl ester
Benzenecarbothioic acid, S-(4,6-diamino-2-pyrimidinyl) ester
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