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CAS No.: | 106-25-2 |
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Name: | 2,6-Octadien-1-ol,3,7-dimethyl-, (2Z)- |
Article Data: | 188 |
Molecular Structure: | |
Formula: | C10H18O |
Molecular Weight: | 154.252 |
Synonyms: | cis-Geraniol;b-Nerol;2,6-Octadien-1-ol,3,7-dimethyl-, (Z)- (8CI);Nerol (6CI);(2Z)-3,7-Dimethyl-2,6-octadien-1-ol;(Z)-3,7-Dimethyl-2,6-octadien-1-ol;(Z)-Geraniol;(Z)-Nerol;2-cis-3,7-Dimethyl-2,6-octadien-1-ol;3,7-Dimethyl-cis-2,6-octadien-1-ol;Nerol900;Neryl alcohol;cis-3,7-Dimethyl-2,6-octadien-1-ol; |
EINECS: | 203-378-7 |
Density: | 0.866 g/cm3 |
Melting Point: | < -10oC |
Boiling Point: | 229.5 °C at 760 mmHg |
Flash Point: | 76.7 °C |
Solubility: | 1.311g/L(25 oC) |
Appearance: | Clear colorless to almost colorless liquid |
Hazard Symbols: | Xi |
Risk Codes: | 36/37/38 |
Safety: | 26-36 |
PSA: | 20.23000 |
LogP: | 2.67140 |
Nerol
Conditions | Yield |
---|---|
With palladium diacetate; sodium azide; trisodium tris(3-sulfophenyl)phosphine In water; acetonitrile at 25℃; for 1h; | 98% |
Conditions | Yield |
---|---|
With isopropyl alcohol; zirconium(IV) oxide for 6h; Rate constant; Heating; | 97% |
With isopropyl alcohol; zirconium(IV) oxide for 6h; Heating; | 97% |
With sodium formate; RuCl2(m-SPPh2)2 In water at 80℃; for 7h; | 95% |
1-(tert-butyldimethylsiloxy)-3,7-dimethyl-2,6-octadiene
Nerol
Conditions | Yield |
---|---|
With acetonyltriphenylphosphonium bromide In methanol; dichloromethane at 20℃; for 0.0833333h; | 95% |
In methanol; dichloromethane for 3.66667h; Irradiation; | |
In methanol; dichloromethane for 3.66667h; Product distribution; Irradiation; other silyl ethers; phenanthrene, var. time; |
Nerol
Conditions | Yield |
---|---|
With lithium; ethylenediamine In tetrahydrofuran at -10℃; for 2h; | 93% |
(Z)-1-(allyloxy)-3,7-dimethylocta-2,6-diene
Nerol
Conditions | Yield |
---|---|
With samarium diiodide; water; isopropylamine In tetrahydrofuran at 20℃; for 0.0333333h; | 88% |
Conditions | Yield |
---|---|
With indium tri-isopropoxide supported on mesoporous SBA-15 In isopropyl alcohol at 80℃; for 7h; Reagent/catalyst; Meerwein-Ponndorf-Verley Reduction; Inert atmosphere; Schlenk technique; chemoselective reaction; | 87.6% |
With potassium hydroxide; isopropyl alcohol; dichlorotetrakis(dimethylsulfoxide)ruthenium at 20℃; for 3h; | 86.8% |
With Triisopropyl borate; isopropyl alcohol at 27℃; for 20h; Kinetics; Reagent/catalyst; Meerwein-Ponndorf-Verley reduction; Inert atmosphere; chemoselective reaction; | 83.1% |
neryl 2-tetrahydropyranyl ether
Nerol
Conditions | Yield |
---|---|
ammonium cerium(IV) nitrate In alkaline aq. solution; acetonitrile at 70℃; for 2h; pH=8; Decomposition; | 86% |
With tin(ll) chloride In methanol Substitution; | 80% |
With boron trifluoride diethyl etherate; dimethylthio-dimethyl-tin In toluene at -20 - 0℃; for 12h; | 82 % Chromat. |
ethyl 3,7-dimethyl-2,6-octadienoate
Nerol
Conditions | Yield |
---|---|
With lithium aluminium tetrahydride | 81% |
With diisobutylaluminium hydride In diethyl ether; hexane at -78 - 20℃; for 12.5h; | 0.9 g |
morpholide of 1-hydroxy-3,7-dimethylocta-2Z,6-diene-4-sulfonic acid
A
Nerol
B
2,6-dimethyl-2,5-octadien-8-ol
Conditions | Yield |
---|---|
With dibenzo-18-crown-6; sodium In tetrahydrofuran; benzene-d6 at -70℃; for 0.0333333h; | A 75% B 4% |
With dibenzo-18-crown-6; sodium In ammonia at -70℃; for 2h; | A 75% B 4% |
With sodium; tert-butyl alcohol In benzene-d6 at -70℃; Yield given. Yields of byproduct given; | |
With lithium; tert-butyl alcohol In ammonia at -70℃; Product distribution; also Na, (DB18C6) or Na, tBuOH in NH3; | |
With lithium In diethyl ether; ammonia at -65℃; Product distribution; other reagent, solvent, temperature; |
Conditions | Yield |
---|---|
With tris(2,4,6-trimethoxyphenyl)phosphine In methanol at 50℃; for 24h; | 73% |
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