CAS No.124-30-1,Octadecanamine Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	124-30-1
Name:	Octadecanamine
Article Data:	57

Formula:	C₁₈H₃₉N
Molecular Weight:	269.514
Synonyms:	Armeen 18;Armeen 18D;Armeen 18D-FLK;Armofilm;Farmin 80;Genamin SH 100;Kemamine P 990D;Monooctadecylamine;NSC 9857;Nissan Amine AB;ODA;Stearamine;Stearylamine;n-Octadecylamine;n-Stearylamine;1-Aminooctadecane;1-Octadecylamine;Adogenen 142;Alamine 7;Alamine7D;Amine 18D;Amine AB;
EINECS:	204-695-3
Density:	0.818 g/cm³
Melting Point:	50-60 °C
Boiling Point:	348.875 °C at 760 mmHg
Flash Point:	154.077 °C
Solubility:	practically insoluble in water
Appearance:	white solid
Hazard Symbols:	Xi
Risk Codes:	36/37/38-41-38
Safety:	26-36-37/39-28B
Transport Information:	UN 3259
PSA:	26.02000
LogP:	6.90690

Synthetic route

: 638-65-3
stearonitrile

: 124-30-1
1-aminooctadecane

Conditions

Conditions	Yield
With sodium hydroxide; hydrogen; nickel In water at 135℃; under 14251.4 Torr; for 3h;	98.2%
With [Ru(H)(BH4)(CO)(PPh3)(3-(di-tert-butylphosphino)-N-((1-methyl-1H-imidazol-2 yl)methyl)propylamine)]; hydrogen In isopropyl alcohol at 70℃; for 3h; Inert atmosphere; Autoclave;	88%
With [bis(2-methylallyl)cycloocta-1,5-diene]ruthenium(II); {[(phenylphosphinediyl)bis(2,1-phenylene)]bis(methylene)}bis(di-tert-butylphosphine); hydrogen In isopropyl alcohol at 70℃; under 11251.1 Torr; for 17h; Inert atmosphere; Autoclave;	72%

: 20332-12-1
2-octadecylisoindoline-1,3-dione

: 124-30-1
1-aminooctadecane

Conditions

Conditions	Yield
With hydrazine hydrate In methanol at 95℃; for 1h; Gabriel Amine Synthesis;	95%

: 1262670-57-4
N-trityloctadecan-1-amine

: 124-30-1
1-aminooctadecane

Conditions

Conditions	Yield
With ammonium cerium (IV) nitrate; water; acetic acid In dichloromethane at 20℃; for 40h; Inert atmosphere;	93%

: 38428-49-8
N-Boc-octadecylamine

: 124-30-1
1-aminooctadecane

Conditions

Conditions	Yield
With 3-butyl-l-methyl-1H-imidazol-3-iumtrifloroacetate In 1,4-dioxane; water at 80℃; for 1.5h;	92%
With methanol; Amberlyst 15; ammonia 1.) CH2Cl2, 25 deg C, 14 h, 2.) 50 min; Yield given. Multistep reaction;

: 3906-22-7
N-octadecylacetamide

: 124-30-1
1-aminooctadecane

Conditions

Conditions	Yield
Stage #1: N-octadecylacetamide With Schwartz's reagent In tetrahydrofuran at 20℃; for 0.0333333h; Inert atmosphere; Stage #2: With water In tetrahydrofuran Inert atmosphere;	91%

: 112-92-5
1-octadecanol

A: 112-99-2
Dioctadecylamine

B: 124-30-1
1-aminooctadecane

Conditions

Conditions	Yield
With ammonia; hydrogen; catalyst formed by supporting 2percent by mass of ruthenium on zirconia surface-treated with sulfur at 220℃; under 120012 Torr; for 2.8h; Product distribution / selectivity; Autoclave;	A 7.4% B 84.8%
Stage #1: 1-octadecanol With hydrogen; catalyst with 35weight percent Ni, 6weight percent Cu, 27weight percent Zr, 0.4weight percent La at 200℃; for 2h; Gas phase; Stage #2: With ammonia; hydrogen; catalyst with 35weight percent Ni, 6weight percent Cu, 27weight percent Zr, 0.4weight percent La at 220℃; for 6h; Product distribution / selectivity;
Stage #1: 1-octadecanol With hydrogen; catalyst with 31weight percent Ni, 12weight percent Cu at 200℃; for 2h; Gas phase; Stage #2: With ammonia; hydrogen; catalyst with 31weight percent Ni, 12weight percent Cu at 220℃; for 9h; Product distribution / selectivity;

: 3386-33-2
1-chlorooctadecane

: 124-30-1
1-aminooctadecane

Conditions

Conditions	Yield
With ammonia at 50℃;

: 112-61-8
Methyl stearate

A: 112-99-2
Dioctadecylamine

B: 124-30-1
1-aminooctadecane

Conditions

Conditions	Yield
With ammonia; hydrogen; cobalt at 270℃; under 147102 - 183877 Torr;
With ammonia; hydrogen; cobalt; decalin at 270℃; under 147102 - 183877 Torr;
With ammonia; cobalt at 270℃; under 147102 - 183877 Torr; Hydrogenation;

: 112-99-2
Dioctadecylamine

: 124-30-1
1-aminooctadecane

Conditions

Conditions	Yield
With aluminium oxide hydrate-kaolin; ammonia at 380℃; under 147102 Torr;

: 124-26-5
stearamide

: 124-30-1
1-aminooctadecane

Conditions

Conditions	Yield
With lithium aluminium tetrahydride; diethyl ether
With lithium aluminium tetrahydride In tetrahydrofuran
With lithium aluminium tetrahydride In tetrahydrofuran for 1h;

Raw Materials

112-99-2

112-90-3

3906-22-7

57-11-4

3386-33-2

112-61-8

112-76-5

124-26-5

Downstream Products

121955-20-2

638-65-3

2877-26-1

629-78-7

629-79-8

25417-58-7

17369-09-4

10213-78-2

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Chemistry

Product Name: Octadecanamine (CAS NO.124-30-1)

Molecular Formula: C₁₈H₃₉N
Molar mass: 269.51 g/mol
Flash Point: 148 °C
Melting point: 50-60 °C
Boiling Point: 349°C
Vapour Pressure: 10 mm Hg ( 72 °C)
Density: 0.862 g/cm³
Refractive index 1.4522
FreezingPoint: 53.1°C
Water solubility: practically insoluble
Appearance: White prills
Surface Tension: 31 dyne/cm
Enthalpy of Vaporization: 59.33 kJ/mol
Vapour Pressure: 4.88E-05 mmHg at 25°C
Index of Refraction: 1.452
Molar Refractivity: 88.97 cm3
Molar Volume: 329.3 cm3
XLogP3-AA: 8.5
H-Bond Donor: 1
H-Bond Acceptor: 1
Structure Descriptors of Octadecanamine (CAS NO.124-30-1):
IUPAC Name: octadecan-1-amine
Canonical SMILES: CCCCCCCCCCCCCCCCCCN
InChI: InChI=1S/C18H39N/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19/h2-19H2,1H3
InChIKey: REYJJPSVUYRZGE-UHFFFAOYSA-N
Product Categories: Alkylamines; Monofunctional & alpha,omega-Bifunctional Alkanes; Monofunctional Alkanes

Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LD50	intraperitoneal	250mg/kg (250mg/kg)		National Technical Information Service. Vol. AD691-490,
mouse	LD50	oral	3gm/kg (3000mg/kg)	BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)	Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 38(11), Pg. 31, 1973.
rat	LD50	oral	2395mg/kg (2395mg/kg)	BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)	Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 38(11), Pg. 31, 1973.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by intraperitoneal route. Moderately toxic by ingestion. A skin irritant. When heated to decomposition it emits toxic fumes of NOx. See also AMINES.
Safety Information of Octadecanamine (CAS NO.124-30-1):
Hazard Codes:Xi
Risk Statements:
36: Irritating to the eyes
37: Irritating to the respiratory system
38: Irritating to the skin
41: Risk of serious damage to eyes
Safety Statements:
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
28: After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer)
36: Wear suitable protective clothing
37: Wear suitable gloves
39: Wear eye/face protection
RIDADR: 3259
WGK Germany: 2
RTECS: RG4150000
HazardClass: 8
PackingGroup: III
HS Code: 29211980

Specification

Octadecanamine , its CAS NO. is 124-30-1, the synonyms are Adogenen 142 ; 1-Octadecanamine ; adogenen142 ; Alamine 7 ; Alamine 7D ; Amine 18-90 .