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CAS No.: | 13200-60-7 |
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Name: | ethyl 2-(methylamino)acetate |
Article Data: | 22 |
Molecular Structure: | |
Formula: | C5H11NO2 |
Molecular Weight: | 117.148 |
Synonyms: | Glycine,N-methyl-,ethyl ester;HNMeCH2CO2Et;ethyl ester of sarcosine;H-Sar-OEt?HCl;ethyl n-methylglycinate;ethyl sarcosinate;sarcosine ethyl ester;N-methylglycine ethyl ester; |
Density: | 0.949g/cm3 |
Boiling Point: | 138.6°Cat760mmHg |
Flash Point: | 37.6°C |
PSA: | 38.33000 |
LogP: | 0.15980 |
Conditions | Yield |
---|---|
In acetonitrile at 0 - 20℃; | 85% |
In diethyl ether; benzene |
Conditions | Yield |
---|---|
With hydrogenchloride for 2h; Heating; | 80% |
With thionyl chloride for 5h; Reflux; | 65% |
With hydrogenchloride |
ethanol
Glyoxal
methylamine
A
N1,N2-dimethylglycinamide
B
Sarcosine ethyl ester
Conditions | Yield |
---|---|
im Rohr; reagiert analog mit anderen Alkyl- und Dialkylaminen; |
Conditions | Yield |
---|---|
With hydrogenchloride |
Conditions | Yield |
---|---|
With water unter Einleiten von Kohlendioxyd und Kochen des entstandenen Nitrils mit alkoh. Salzsaeure auf dem Wasserbad; |
ethanol
methylamine
A
N1,N2-dimethylglycinamide
B
Sarcosine ethyl ester
sarcosine ethyl ester hydrochloride
triethylamine
A
Sarcosine ethyl ester
B
triethylamine hydrochloride
Conditions | Yield |
---|---|
In dichloromethane |
tert-butoxycarbonyl-methyl-amino-acetic acid ethyl ester
Sarcosine ethyl ester
Conditions | Yield |
---|---|
With trifluoroacetic acid In dichloromethane at 0 - 20℃; |
sarcosine ethyl ester hydrochloride
Sarcosine ethyl ester
Conditions | Yield |
---|---|
With water | |
In water |
methylamine hydrochloride
chloroacetic acid ethyl ester
Sarcosine ethyl ester
Conditions | Yield |
---|---|
Stage #1: methylamine hydrochloride With potassium carbonate In acetonitrile at 15℃; for 1.5h; Stage #2: chloroacetic acid ethyl ester In acetonitrile at 20℃; for 10h; | |
With potassium carbonate In acetonitrile at 20℃; for 10h; | |
Stage #1: methylamine hydrochloride With triethylamine In acetonitrile at 15℃; for 1.5h; Stage #2: chloroacetic acid ethyl ester In acetonitrile at 20℃; for 10h; |