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CAS No.: | 1806-54-8 |
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Name: | trioctyl phosphate |
Article Data: | 12 |
Molecular Structure: | |
Formula: | C24H51 O4 P |
Molecular Weight: | 434.64 |
Synonyms: | Octylphosphate ((C8H17O)3PO) (6CI,7CI); Tri-n-octyl phosphate; Trioctyl phosphate |
EINECS: | 217-305-1 |
Density: | 0.928g/cm3 |
Melting Point: | -74 C |
Boiling Point: | 414.6°Cat760mmHg |
Flash Point: | 218°C |
Solubility: | Toxicity data (The meaning of a"> insoluble
Stability
Toxicology
Toxicity data |
Appearance: | colourless viscous liquid |
PSA: | 54.57000 |
LogP: | 9.22580 |
Conditions | Yield |
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With trichlorophosphate In cyclohexanone at 10 - 30℃; under 10 Torr; for 4h; | 97.6% |
With sodium hexachloroplatinate; phosphan at 174.9℃; Rate constant; Mechanism; var. temp., other alcohols; | |
With pyridine; diethyl ether; trichlorophosphate | |
With sodium hexachloroplatinate; phosphan at 25 - 40℃; Condensation; | |
With pyridine; iodine; triphenylphosphine at 50℃; under 1.7E-05 Torr; Kinetics; | 100 % Chromat. |
Conditions | Yield |
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With phosphan; chlorine Rate constant; Thermodynamic data; Ea, ΔS(excit.); also in the presence of pyridine; |
tri-n-octyl phosphate
Conditions | Yield |
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With trichlorophosphate at 30 - 55℃; | |
With trichlorophosphate at 30 - 55℃; |
octanol
diphenylzinc
A
tri-n-octyl phosphate
B
octyl phenyl(phenyl)phosphinate
C
dioctyl phenylphosphonate
Conditions | Yield |
---|---|
Stage #1: diphenylzinc With trichlorophosphate In diethyl ether at 20℃; for 21.5h; Inert atmosphere; Stage #2: octanol With pyridine In diethyl ether at 20℃; for 29h; Inert atmosphere; | A n/a B n/a C 0.55 g |
tri-n-octyl phosphate
toluene-4-sulfonic acid
A
1-octyl p-toluenesulfonate
B
4-sec-octyltoluene
Conditions | Yield |
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In toluene for 9h; Heating; | A 30% B 60% |
tri-n-octyl phosphate
toluene-4-sulfonic acid
toluene
A
1-octyl p-toluenesulfonate
B
4-sec-octyltoluene
Conditions | Yield |
---|---|
In toluene for 9h; Heating; | A 30% B 60% |
Conditions | Yield |
---|---|
Stage #1: maleic anhydride; tri-n-octyl phosphate; aluminum (III) chloride In chlorobenzene at 10℃; Stage #2: 1,2-dimethoxybenzene In chlorobenzene at 10 - 15℃; for 4h; Product distribution / selectivity; | 59.8% |
tri-n-octyl phosphate
phosphoric acid dioctyl ester; magnesium salt
Conditions | Yield |
---|---|
With magnesium bromide In dichloromethane Heating; |
tri-n-octyl phosphate
trichlorophosphate
A
hydrogenchloride
B
1-Chlorooctane
C
oct-1-ene
Conditions | Yield |
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