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CAS No.: | 19962-06-2 | ||||||
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Name: | N-BOC-3-AMINOPHENOL | ||||||
Article Data: | 49 | ||||||
Molecular Structure: | |||||||
Formula: | C11H15 N O3 | ||||||
Molecular Weight: | 209.245 | ||||||
Synonyms: | Carbamicacid, (3-hydroxyphenyl)-, 1,1-dimethylethyl ester (9CI); Carbanilic acid,m-hydroxy-, tert-butyl ester (8CI); 1,1-Dimethylethyl(3-hydroxyphenyl)carbamate; 3-(tert-Butoxycarbonylamino)phenol; NSC 222586;tert-Butyl 3-hydroxyphenylcarbamate | ||||||
Density: | 1.182g/cm3 | ||||||
Melting Point: | 134-138 °C(lit.) | ||||||
Boiling Point: | 286.8°Cat760mmHg | ||||||
Flash Point: | 127.3°C | ||||||
Hazard Symbols: | |||||||
Risk Codes: | 43 | ||||||
Safety: |
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PSA: | 58.56000 | ||||||
LogP: | 2.81220 |
di-tert-butyl dicarbonate
m-Hydroxyaniline
tert-butyl 3-hydroxyphenylcarbamate
Conditions | Yield |
---|---|
In tetrahydrofuran Reflux; | 100% |
In tetrahydrofuran for 24h; Heating; | 96% |
In tetrahydrofuran for 18h; Reflux; | 95% |
m-Hydroxyaniline
tert-butyl 3-hydroxyphenylcarbamate
Conditions | Yield |
---|---|
In ethanol for 1h; Reflux; | 94% |
di-tert-butyl dicarbonate
3-azidophenol
tert-butyl 3-hydroxyphenylcarbamate
Conditions | Yield |
---|---|
With hydrogen; Lindlar's catalyst In methanol at 20℃; under 760 Torr; for 6h; | 89% |
tert-butyl 3-hydroxyphenyl(3-perfluorooctylpropoxy)carbamate
tert-butyl 3-hydroxyphenylcarbamate
Conditions | Yield |
---|---|
With methanol; tris(propionitrile)tricarbonylmolybdenum(0) at 130℃; for 0.25h; Microwave irradiation; Inert atmosphere; chemoselective reaction; |
tert-butyl 3-hydroxyphenylcarbamate
4-fluoro-2-methylaminonitrobenzene
tert-butyl {3-[3-(methylamino)-4-nitrophenoxy]phenyl}carbamate
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide at 100℃; for 14h; | 100% |
tert-butyl 3-hydroxyphenylcarbamate
propargyl bromide
tert-butyl 3-(prop-2-ynyloxy)phenylcarbamate
Conditions | Yield |
---|---|
With potassium carbonate; sodium iodide In N,N-dimethyl-formamide at 68℃; for 45h; | 98% |
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 12h; | 80% |
2,2,2-trifluoroethyl trifluoromethanesulphonate
tert-butyl 3-hydroxyphenylcarbamate
tert-butyl (3-(2,2,2-trifluoroethoxy)phenyl)carbamate
Conditions | Yield |
---|---|
With potassium carbonate In acetone at 50℃; | 97% |
With potassium carbonate In acetone at 50℃; for 36h; | 97.3% |
tert-butyl 3-hydroxyphenylcarbamate
2,4-dichloro-5-fluoropyrimidine
C15H15ClFN3O3
Conditions | Yield |
---|---|
With N-ethyl-N,N-diisopropylamine In butan-1-ol at 110℃; for 16h; | 96% |
4-chloro-3-nitro-2-pyridinamine
tert-butyl 3-hydroxyphenylcarbamate
4-(3-N-(tert-butoxycarbonyl)aminophenoxy)-3-nitropyridin-2-amine
Conditions | Yield |
---|---|
Stage #1: tert-butyl 3-hydroxyphenylcarbamate With potassium tert-butylate In N,N-dimethyl-formamide at 20℃; for 1h; Inert atmosphere; Stage #2: 4-chloro-3-nitro-2-pyridinamine In N,N-dimethyl-formamide at 80℃; for 20h; Inert atmosphere; Further stages; | 96% |
2-(bromomethyl)-6-(2,5-dimethyl-1H-pyrrol-1-yl)-4-methylpyridine
tert-butyl 3-hydroxyphenylcarbamate
tert-butyl (3-((6-(2,5-dimethyl-1H-pyrrol-1-yl)-4-methylpyridin-2-yl)methoxy)phenyl)-carbamate
Conditions | Yield |
---|---|
With potassium carbonate In acetone for 8h; Inert atmosphere; Reflux; | 90% |