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CAS No.: | 22567-17-5 | ||||||
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Name: | (+)-GAMMA-GURJUNENE | ||||||
Molecular Structure: | |||||||
Formula: | C15H24 | ||||||
Molecular Weight: | 204.356 | ||||||
Synonyms: | 1b,4bH,10bH-Guaia-5,11-diene (8CI); Azulene, 1,2,3,3a,4,5,6,7-octahydro-1,4-dimethyl-7-(1-methylethenyl)-,[1R-(1a,3ab,4a,7b)]-; (+)-g-Gurjunene;1,2,3,3a,4,5,6,7-Octahydro-1,4-dimethyl-7-(1-methylethenyl)-[1R-(1a,3ab,4a,7b)]-azulene; 5,11-Guaiadiene; g-Gurjunene | ||||||
Density: | 0.89g/cm3 | ||||||
Boiling Point: | 276.5°Cat760mmHg | ||||||
Flash Point: | 108.9°C | ||||||
Safety: |
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PSA: | 0.00000 | ||||||
LogP: | 4.58110 |
(1aR,4R,7R,7bS)-1,1,4,7-tetramethyl-1a,2,3,4,5,6,7,7b-octahydro-1H-cyclopropa[e]azulene
[1R-(1α,3aβ,4α,7β)]-1,2,3,3a,4,5,6,7-octahydro-1,4-dimethyl-7-(1-methylethenyl)-azulene
Conditions | Yield |
---|---|
at 450℃; | 80% |
[1R-(1α,3aβ,4α,7β)]-1,2,3,3a,4,5,6,7-octahydro-1,4-dimethyl-7-(1-methylethenyl)-azulene
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: K/Al2O3 / 100 °C 2: 80 percent / 450 °C View Scheme | |
Multi-step reaction with 2 steps 1: 100 percent / 10percent K/Al2O3 / hexane / Ambient temperature 2: 80 percent / 450 °C View Scheme |
[1R-(1α,3aβ,4α,7β)]-1,2,3,3a,4,5,6,7-octahydro-1,4-dimethyl-7-(1-methylethenyl)-azulene
(6R,10R)-3-Isopropyl-6,10-dimethyltricyclo[5.3.0]deca-2,7(1)-diene
Conditions | Yield |
---|---|
With fluorosulfonylchloride In dichloromethane at -115℃; Isomerization; | 33% |
[1R-(1α,3aβ,4α,7β)]-1,2,3,3a,4,5,6,7-octahydro-1,4-dimethyl-7-(1-methylethenyl)-azulene
Conditions | Yield |
---|---|
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 25℃; for 12h; Product distribution; var. temp. and time; | A 36 mg B 24 mg C 56 mg D 13 mg |
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 25℃; for 12h; | A 36 mg B 24 mg C 56 mg D 13 mg |
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 25℃; for 4h; | A 36 mg B 24 mg C 56 mg D 13 mg |
[1R-(1α,3aβ,4α,7β)]-1,2,3,3a,4,5,6,7-octahydro-1,4-dimethyl-7-(1-methylethenyl)-azulene
Conditions | Yield |
---|---|
With Glomerella cingulata In water for 240h; culture medium; | A 202 mg B 68 mg |
[1R-(1α,3aβ,4α,7β)]-1,2,3,3a,4,5,6,7-octahydro-1,4-dimethyl-7-(1-methylethenyl)-azulene
A
(1aR,4R,7R,7bS)-1,1,4,7-tetramethyl-1a,2,3,4,5,6,7,7b-octahydro-1H-cyclopropa[e]azulene
B
(6R,7R)-3-Isopropyl-6,10-dimethyltricyclo[5.3.0]deca-2,7(1)-diene
Conditions | Yield |
---|---|
With Sulfate; titanium(IV) oxide In dichloromethane at 20℃; for 0.216667h; Rearrangement; | A n/a B 0.0514 g C 0.0048 g D n/a |
[1R-(1α,3aβ,4α,7β)]-1,2,3,3a,4,5,6,7-octahydro-1,4-dimethyl-7-(1-methylethenyl)-azulene
Conditions | Yield |
---|---|
With hydrogen; nickel on carbon In ethanol; benzene at 25℃; |
[1R-(1α,3aβ,4α,7β)]-1,2,3,3a,4,5,6,7-octahydro-1,4-dimethyl-7-(1-methylethenyl)-azulene
Conditions | Yield |
---|---|
With chicory; enzymes from roots of Cichorium intybus L; NADPH In ethanol for 1h; pH=7.5; Product distribution; Further Variations:; Reagents; Solvents; |