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CAS No.: | 2613-27-6 | ||||||||||||||
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Name: | 4-NITROPHENYLSULFUR PENTAFLUORIDE | ||||||||||||||
Article Data: | 21 | ||||||||||||||
Molecular Structure: | |||||||||||||||
Formula: | C6H4 F5 N O2 S | ||||||||||||||
Molecular Weight: | 249.161 | ||||||||||||||
Synonyms: | (p-Nitrophenyl)sulfurpentafluoride (6CI); Sulfur, pentafluoro(p-nitrophenyl)- (7CI,8CI);4-Nitro(pentafluorosulfanyl)benzene; 4-Nitrobenzenesulfur pentafluoride;4-Nitrophenylsulfur pentafluoride; Pentafluoro(4-nitrophenyl)sulfur | ||||||||||||||
Density: | g/cm3 | ||||||||||||||
Melting Point: | 38 °C | ||||||||||||||
Boiling Point: | 76-77°C 12mm | ||||||||||||||
Flash Point: | °C | ||||||||||||||
Solubility: | Insoluble in water | ||||||||||||||
Hazard Symbols: | |||||||||||||||
Risk Codes: | 34 | ||||||||||||||
Safety: |
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PSA: | 71.12000 | ||||||||||||||
LogP: | 4.77540 |
1-nitro-4-(pentafluorosulfanyl)benzene
Conditions | Yield |
---|---|
With hydrogen fluoride; mercury(II) oxide at -30 - 20℃; Inert atmosphere; Sealed tube; | 81% |
With iodine pentafluoride In neat (no solvent) at 65℃; for 14h; Glovebox; Inert atmosphere; | 75% |
With silver carbonate at 70℃; Inert atmosphere; Glovebox; | 66% |
With zinc(II) fluoride at 150℃; for 72h; Inert atmosphere; | 36% |
With silver tetrafluoroborate In dichloromethane at 20℃; for 14h; Inert atmosphere; | 189.9 mg |
Conditions | Yield |
---|---|
With potassium fluoride; bis(fluoroxy)methane at -20 - -15℃; | 63% |
With silver(II) fluoride In various solvent(s) at 20 - 130℃; | 50% |
With fluorine In acetonitrile at -5℃; for 1h; Inert atmosphere; | 45% |
Conditions | Yield |
---|---|
With fluorine In acetonitrile at 20℃; | 60% |
With fluorine Ambient temperature; | 44% |
With bis(fluoroxy)methane In acetonitrile at -20 - 20℃; | |
With fluorine; cesium fluoride In acetonitrile at -30 - -25℃; | |
With potassium fluoride; bis(fluoroxy)methane In acetonitrile at -15℃; |
Conditions | Yield |
---|---|
In acetonitrile | 28% |
Multi-step reaction with 3 steps 1.1: sodium hydroxide / water / 0.5 h / Inert atmosphere 1.2: 14 h / 20 °C / Inert atmosphere 2.1: potassium fluoride; chlorine / acetonitrile / 20 °C / Inert atmosphere; Glovebox; Cooling with ice 3.1: iodine pentafluoride / neat (no solvent) / 14 h / 65 °C / Glovebox; Inert atmosphere View Scheme | |
Multi-step reaction with 3 steps 1.1: sodium hydroxide / water / 0.5 h / Inert atmosphere 1.2: 12 h / 20 °C / Inert atmosphere 2.1: potassium fluoride; chlorine / acetonitrile / 20 °C / Inert atmosphere; Glovebox; Cooling with ice 3.1: silver carbonate / 70 °C / Inert atmosphere; Glovebox View Scheme |
Conditions | Yield |
---|---|
Stage #1: 4-nitrobenzenesulfenyl chloride With bis(fluoroxy)methane In acetonitrile at -20 - -15℃; Stage #2: With cesium fluoride In acetonitrile | |
Stage #1: 4-nitrobenzenesulfenyl chloride With bis(fluoroxy)methane In acetonitrile at -20 - -15℃; Stage #2: With fluorine; cesium fluoride In acetonitrile at -30 - -25℃; | |
Multi-step reaction with 2 steps 1: potassium fluoride; chlorine / acetonitrile / 5 - 11 °C 2: zinc(II) fluoride / 72 h / 150 °C / Inert atmosphere View Scheme |
di(p-nitrophenyl) disulfide
A
1-nitro-4-(pentafluorosulfanyl)benzene
B
4-nitrophenylsulphur trifluoride
Conditions | Yield |
---|---|
With fluorine In acetonitrile at -35 - -25℃; |
di(p-nitrophenyl) disulfide
A
1-nitro-4-(pentafluorosulfanyl)benzene
B
4-nitrobenzenesulfonyl fluoride
Conditions | Yield |
---|---|
With silver(II) fluoride; copper at 60 - 125℃; for 8h; Sealed tube; | A 6.73 g B n/a |
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1.1: sodium sulfide / N,N-dimethyl-formamide / 4 h / 20 °C / Inert atmosphere 2.1: sodium hydroxide / water / 0.5 h / Inert atmosphere 2.2: 12 h / 20 °C / Inert atmosphere 3.1: potassium fluoride; chlorine / acetonitrile / 20 °C / Inert atmosphere; Glovebox; Cooling with ice 4.1: silver carbonate / 70 °C / Inert atmosphere; Glovebox View Scheme |
Conditions | Yield |
---|---|
With hydrogenchloride; iron In ethanol; water at 0 - 20℃; for 1h; | 100% |
With hydrogen; nickel In ethanol | 99% |
Stage #1: 1-nitro-4-(pentafluorosulfanyl)benzene With hydrogenchloride; tin(ll) chloride In water at 45 - 100℃; for 3.5h; Stage #2: With sodium hydroxide In dichloromethane; water at 0℃; | 99% |
1-nitro-4-(pentafluorosulfanyl)benzene
benzyl alcohol
(4-(benzyloxy)phenyl)pentafluoro-λ6-sulfane
Conditions | Yield |
---|---|
With potassium tert-butylate In N,N-dimethyl-formamide at 20℃; for 1h; Inert atmosphere; | 96% |
With potassium tert-butylate In N,N-dimethyl-formamide at 20℃; for 1h; | 96% |