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CAS No.: | 26555-40-8 | ||||||||||||||||
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Name: | METHOXYCARBONYLSULFENYL CHLORIDE | ||||||||||||||||
Article Data: | 12 | ||||||||||||||||
Molecular Structure: | |||||||||||||||||
Formula: | C2H3 Cl O2 S | ||||||||||||||||
Molecular Weight: | 126.564 | ||||||||||||||||
Synonyms: | Carbonicacid, thio-, anhydrosulfide with thiohypochlorous acid, methyl ester (8CI);Carbonothioic acid, anhydrosulfide with thiohypochlorous acid, O-methyl ester(9CI); Thiohypochlorous acid, anhydrosulfide with O-methyl thiocarbonate (8CI);(Chlorothio)(methoxy)oxomethane; Carbomethoxysulfenyl chloride;Methoxycarbonylsulfenyl chloride; Methyl (chlorosulfenyl)formate | ||||||||||||||||
Density: | 1.4g/cm3 | ||||||||||||||||
Boiling Point: | 133.5°Cat760mmHg | ||||||||||||||||
Flash Point: | 34.5°C | ||||||||||||||||
Appearance: | CLEAR BRIGHT YELLOW LIQUID | ||||||||||||||||
Hazard Symbols: | |||||||||||||||||
Risk Codes: | 10-34 | ||||||||||||||||
Safety: |
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PSA: | 51.60000 | ||||||||||||||||
LogP: | 1.63980 |
Conditions | Yield |
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In diethyl ether for 16h; Heating; | 88% |
In diethyl ether | |
In tetrahydrofuran at 0℃; for 0.25h; |
methanol
(fluorocarbonyl)sulfenyl chloride
Methoxycarbonylsulfenyl chloride
Conditions | Yield |
---|---|
equimolar amts. of educts; | 20% |
bis-methoxycarbonyl-disulfane
Methoxycarbonylsulfenyl chloride
Conditions | Yield |
---|---|
With chlorine |
bis(methoxycarbonyl)sulfide
Methoxycarbonylsulfenyl chloride
Conditions | Yield |
---|---|
With sulfuryl dichloride; chlorine |
((Methoxycarbonyl)dithio)carbonyl Chloride
Methoxycarbonylsulfenyl chloride
Conditions | Yield |
---|---|
In chloroform-d1 at 62℃; | |
In chloroform-d1 at 62℃; Rate constant; |
chloro(chlorosulfanyl)methanone
Methoxycarbonylsulfenyl chloride
Conditions | Yield |
---|---|
In methanol |
Conditions | Yield |
---|---|
In methanol |
Methoxycarbonylsulfenyl chloride
3-mercaptopropionic acid
Conditions | Yield |
---|---|
In dichloromethane at 0 - 20℃; Inert atmosphere; | 100% |
With N,O-bis-(trimethylsilyl)-acetamide 1.) CH2Cl2, 1.5 h, 2.) CH2Cl2, 25 deg C, 2 h; Yield given. Multistep reaction; |
Methoxycarbonylsulfenyl chloride
2-(4-fluorophenoxy)-5-(((4R)-4-((methoxycarbonyl)dithio)-2-oxo-1-pyrrolidinyl)methyl)pyridine
Conditions | Yield |
---|---|
In methanol at 20℃; for 0.5h; | 100% |
Methoxycarbonylsulfenyl chloride
4-mercaptophenylacetic acid
Conditions | Yield |
---|---|
In dichloromethane at 0 - 20℃; Inert atmosphere; | 100% |