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33404-78-3

Basic Information
CAS No.: 33404-78-3
Name: negamycin
Article Data: 19
Molecular Structure:
Molecular Structure of 33404-78-3 (negamycin)
Formula: C9H20 N4 O4
Molecular Weight: 248.282
Synonyms: Aceticacid, [2-(3,6-diamino-5-hydroxyhexanoyl)-1-methylhydrazino]- (8CI);(+)-Negamycin; Negamycin
Density: 1.303g/cm3
Melting Point: 110-120° (dec)
PSA: 145.40000
LogP: -0.29800
Synthetic route
1037825-22-1

(R)-tert-butyl (R)-5-[2-(tert-butoxycarbonylamino)-3-{(tert-butoxycarbonylmethyl)methylaminocarbamoyl}propyl]-2,2-dimethyloxazolidine-3-carboxylate

33404-78-3

negamycin

Conditions
ConditionsYield
With hydrogenchloride In 1,4-dioxane at 0℃; for 2h;98%

[N'-((3R,5R)-3-Amino-6-benzyloxycarbonylamino-5-hydroxy-hexanoyl)-N-methyl-hydrazino]-acetic acid benzyl ester

33404-78-3

negamycin

Conditions
ConditionsYield
With hydrogen; acetic acid; palladium on activated charcoal In methanol under 2250.2 Torr; for 12h; Ambient temperature;96%
1613376-41-2

2-((3R,5R)-2-benzyloxycarbonyl-5-(chloromethyl)isoxazolidinyl)acetic acid

33404-78-3

negamycin

Conditions
ConditionsYield
With palladium 10% on activated carbon; hydrogen; acetic acid In methanol; water at 20℃; under 2068.65 Torr; for 24h;94%

{N'-[(3R,5R)-6-Azido-5-hydroxy-3-((4S,5R)-2-oxo-4,5-diphenyl-oxazolidin-3-yl)-hexanoyl]-N-methyl-hydrazino}-acetic acid benzyl ester

33404-78-3

negamycin

Conditions
ConditionsYield
With hydrogen; acetic acid; palladium on activated charcoal In methanol under 2068.6 Torr; for 8h; Ambient temperature;91%
119138-84-0

[N'-((3R,5R)-3,6-Diazido-5-benzyloxymethoxy-hexanoyl)-N-methyl-hydrazino]-acetic acid benzyl ester

33404-78-3

negamycin

Conditions
ConditionsYield
With hydrogen; palladium on activated charcoal In methanol; acetic acid89%
540721-28-6

[N'-(6-amino-3-tert-butoxycarbonylamino-5-hydroxy-hexanoyl)-N-methyl-hydrazino]-acetic acid tert-butyl ester

33404-78-3

negamycin

Conditions
ConditionsYield
With hydrogenchloride In 1,4-dioxane at 20℃; for 9h;78%
103321-73-9

benzyl (3R,5R)-<2-isoxazolidin-3-yl>acetyl>-1-methylhydrazino>acetate

33404-78-3

negamycin

Conditions
ConditionsYield
With hydrogen; palladium on activated charcoal In methanol; acetic acid under 2280 Torr; for 12h;75%
With methanol; hydrogen; acetic acid; palladium on activated charcoal under 2280 Torr; for 12h;75%
461385-14-8

(2S,3R,6R)-6-[(R)-2-(Benzyl-benzyloxycarbonyl-amino)-3-(N'-benzyloxycarbonylmethyl-N'-methyl-hydrazinocarbonyl)-propyl]-2,3-diphenyl-morpholine-4-carboxylic acid benzyl ester

33404-78-3

negamycin

Conditions
ConditionsYield
With hydrogen; acetic acid; palladium on activated charcoal In methanol; water at 75℃; under 2068.65 Torr; for 4.25h;75%
119688-96-9

{N'-[(3R,5R)-3,6-Diazido-5-(tert-butyl-dimethyl-silanyloxy)-hexanoyl]-N-methyl-hydrazino}-acetic acid benzyl ester

33404-78-3

negamycin

Conditions
ConditionsYield
With hydrogen; acetic acid; palladium on activated charcoal In methanol at 20℃;72%
With hydrogen; palladium on activated charcoal In 1,4-dioxane; hydrogenchloride

tert-butyl 2-(2-((3R,5R)-6-azido-5-((tert-butyldimethylsilyl)oxy)-3-(1,1-dimethylethylsulfinamido)hexanoyl)-1-methylhydrazinyl)acetate

33404-78-3

negamycin

Conditions
ConditionsYield
Stage #1: tert-butyl 2-(2-((3R,5R)-6-azido-5-((tert-butyldimethylsilyl)oxy)-3-(1,1-dimethylethylsulfinamido)hexanoyl)-1-methylhydrazinyl)acetate With palladium 10% on activated carbon; hydrogen In methanol at 20℃; for 4h;
Stage #2: With hydrogenchloride In methanol; water at 20℃; for 2h;
68%
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    Hubei Jusheng Technology Co., Ltd., is a large group corporation which engaged in the R&D and manufacture of chemicals, Pharmaceuticals and intermediates. We have earned ourselves

  • Hubei Jusheng Technology Co., Ltd.,

     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:+86-18871490254

    Address:High-tech Industrial Park,Tianmen city,Hubei province.

       Inquiry Now

  • L-threo-Hexonic acid,3,6-diamino-2,3,4,6-tetradeoxy-, 2-(carboxymethyl)-2-methylhydrazide

  • Casno:

    33404-78-3

    L-threo-Hexonic acid,3,6-diamino-2,3,4,6-tetradeoxy-, 2-(carboxymethyl)-2-methylhydrazide

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

    Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers. Prompt reaction, good quality and best service make us reliable and outstanding in this industry.Appearance:yellow to white solid or po

    HEBEI MINGXING BIOTECH CO.,LTD is a international firm starts its exporting business since Sept,2010.Our company was registered legally in Shijiazhuang Administration of Industry a

  • Hebei mingxing biotech co.,ltd

    China (Mainland)  |  Contact Details

    Business Type:Other

    Tel:0311-69115445

    Address:No 29,Phoenix Town,Jianhua south street,Yuhua district

       Inquiry Now

  • NEGAMYCIN

  • Casno:

    33404-78-3

    NEGAMYCIN

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

    We are a trading company aiming at providing high-quality services to customers. Established for many years, with good reputation in the industry Storage:Sealed and preserved Application:Fine chemical intermediates, used as the main raw material for

    Shandong Jiashisheng Biotechnolgy Co.,Ltd is located in high-tech Zone, Liaocheng City, Shandong Province, China, old factory was found in 2008, also named Jiashisheng Group. Here

  • Shandong Jiashisheng Biotechnolgy Co.,Ltd

     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:13165407087

    Address:Bock B, Yunshang Building, High-tech Zone

       Inquiry Now

  • NEGAMYCIN

  • Casno:

    33404-78-3

    NEGAMYCIN

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

    NEGAMYCINAppearance:white crystalline powder Storage:Shading, sealed, dry place. Package:aluminous bag Application:API Transportation:SEA OR AIR

    Locating in Changchun bonded area, which has absolute advantage of importing and exporting, with the R&D team having more than 10 years experience of OLED material and intermediate

  • changchun tuocai technology co.,ltld

    China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:86-431-81292405

    Address:no.7299,airport road

       Inquiry Now

  • NEGAMYCIN

  • Casno:

    33404-78-3

    NEGAMYCIN

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

    We are a trading company aiming at providing high-quality services to customers. Established for many years, with good reputation in the industry Storage:Sealed and preserved Application:Fine chemical intermediates, used as the main raw material for

    Our company has been engaged in the Pharmaceutical raw material and pharmaceutical intermediates medicine material intermediates and related chemical industry for more than ten ye

  • Taizhou volsen chemical Co., Ltd

     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86-576-88869393

    Address:Jiaojiang District, Taizhou, Zhejiang, China.

       Inquiry Now

  • 33404-78-3

  • Casno:

    33404-78-3

    33404-78-3

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

    NEGAMYCIN Application:API

    We are Hebei minshang biotechnology co. LTD., mainly deal in pharmaceutical intermediates and various chemicals. We are manufacturers and have our own factory. Products & Usage Ph

  • Hebei Minshang Biotechnology Co., Ltd

    China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:18032092709

    Address:hebei

       Inquiry Now

  • NEGAMYCIN

  • Casno:

    33404-78-3

    NEGAMYCIN

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

    NEGAMYCINAppearance:white crystalline powder Storage:Shading, sealed, dry place. Package:aluminous bag Application:API Transportation:SEA OR AIR

    Shanghai PengMo Biotechnology Co., Ltd. is engaging in researching, developing, manufacturing and exporting advanced pharmaceutical intermediates and other fine chemicals. Our comp

  • Shanghai PengMo Biotechnology Co.,Ltd

     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:86-13052359378

    Address:No.218 Hai Qu Road.Shanghai.China

       Inquiry Now

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