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CAS No.: | 373-80-8 |
---|---|
Name: | TRIFLUOROMETHYLSULFUR PENTAFLUORIDE |
Article Data: | 33 |
Molecular Structure: | |
Formula: | CF8 S |
Molecular Weight: | 196.064 |
Synonyms: | (Trifluoromethyl)sulfurpentafluoride (6CI); Sulfur, pentafluoro(trifluoromethyl)- (7CI,8CI);(Trifluoromethyl)pentafluorosulfur; Pentafluoro(trifluoromethyl)sulfur |
Density: | g/cm3 |
Melting Point: | -87°C |
Boiling Point: | -21 °C |
Flash Point: | °C |
Risk Codes: | 23-34 |
Safety: | 3/7-9-26-36/37/39-45 |
PSA: | 25.30000 |
LogP: | 3.80470 |
Bis(trifluoromethyl)disulfid
chlorine monofluoride
A
trifluoromethyl sulfur pentafluoride
B
trans-chlorotetrafluoro(trifluoromethyl)sulfur(VI)
Conditions | Yield |
---|---|
molar ratio of CF3SSCF3 and ClF = 1:8.5 to 1:9, 10 h, 25°c; | A <1 B 76.8% |
molar ratio of CF3SSCF3 and ClF = 1:8.5 to 1:9, 10 h, 25°c; | A <1 B 76.8% |
Conditions | Yield |
---|---|
250°C; | 40% |
250°C; | 40% |
Conditions | Yield |
---|---|
250-275°C , diluted with N2; | 20% |
250-275°C , diluted with N2; | 20% |
190-210°C , diluted with N2; | 15% |
1-butanethiol
hydrogen fluoride
A
pentafluoro(1,1,2,2,2-pentafluoroethyl)-λ6-sulfane
B
n-C4F9SF5
C
trifluoromethyl sulfur pentafluoride
Conditions | Yield |
---|---|
In further solvent(s) Electrochem. Process; electrofluorination in anhyd. HF for 6 h 40 min 15°C, helium flow rate 60 mL/min, U=5.8-8.0 V, i=2.9 A/dm2; | A n/a B 12.3% C n/a |
In further solvent(s) Electrochem. Process; electrofluorination in anhyd. HF for 6 h 40 min 15°C, helium flow rate 60 mL/min, U=5.8-8.0 V, i=2.9 A/dm2; | A n/a B 12.3% C n/a |
Conditions | Yield |
---|---|
48°C , T-reactor, CS2:F2:N2=1:5:75; | 9% |
48°C , T-reactor, CS2:F2:N2=1:5:75; | 9% |
40°C , diluted with N2; | |
40°C , diluted with N2; |
Conditions | Yield |
---|---|
With hydrogen fluoride elektrochemische Fluorierung an einer Nickel-Anode; | |
With cobalt (III) fluoride at 250℃; | |
electrofluorination; |
carbon disulfide
A
trifluoromethyl sulfur pentafluoride
B
trifluoro(trifluoromethyl)sulfur(IV)
Conditions | Yield |
---|---|
With silver(II) fluoride |
bis(trifluoromethyl)trithiocarbonate
A
Bis(trifluoromethyl)disulfid
B
trifluoromethyl sulfur pentafluoride
C
trifluoro(trifluoromethyl)sulfur(IV)
D
trifluoromethanesulfinyl fluoride
Conditions | Yield |
---|---|
With silver(II) fluoride; sodium fluoride In 1,1,2-Trichloro-1,2,2-trifluoroethane | |
With silver(II) fluoride; sodium fluoride |
hydrogen fluoride
[1,3,5]trithiane
A
trifluoromethyl sulfur pentafluoride
B
(difluoromethanediyl)bis(pentafluorosulfur(VI))
C
pentafluorothiodifluoromethyl-trifluoromethylsulfurtetrafluoride
Conditions | Yield |
---|---|
Electrolysis; |
Conditions | Yield |
---|---|
at 200 - 250℃; |