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| CAS No.: | 3811-49-2 |
|---|---|
| Name: | SALITHION |
| Article Data: | 8 |
| Molecular Structure: | |
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| Formula: | C8H9 O3 P S |
| Molecular Weight: | 216.197 |
| Synonyms: | Phosphorothioicacid, O-methyl ester, cyclic O,O-ester with o-hydroxybenzyl alcohol (7CI);Phosphorothioic acid, cyclic O,O-(methylene-o-phenylene) O-methyl ester (8CI);Benzyl alcohol, o-hydroxy-, cyclic O,O-ester with O-methyl phosphorothioate(8CI); 2-Methoxy-4H-1,3,2-benzodioxaphorphorin-2-sulfide;2-Methoxy-4H-1,3,2-benzodioxaphospholin-2-sulfide; 2-Methoxy-4H-1,3,2-benzodioxaphosphorin-2-sulfide;Dioxabenzofos; Dioxabenzophos; Fenfosphorin; Saligenin cyclic methylphosphorothionate; Salithion |
| Density: | 1.37g/cm3 |
| Melting Point: | 52.5oC |
| Boiling Point: | 274.4°Cat760mmHg |
| Flash Point: | 119.8°C |
| Solubility: | 43 mg l-1 |
| Hazard Symbols: |
 
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| Risk Codes: | 24/25-39/25-51/53 |
| Safety: | Poison by ingestion, skin contact, and subcutaneous routes. Mutation data reported. An insecticide. When heated to decomposition it emits very toxic fumes of SOx and POx. See also PARATHION. |
| PSA: | 69.59000 |
| LogP: | 3.11710 |
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Chemistry
Product Name: 2-Methoxy-4H-1,2,3-benzodioxaphosphorine-2-sulfide (CAS NO.3811-49-2)
Molecular Formula: C8H9O3PS
Molecular Weight: 216.19g/mol
Mol File: 3811-49-2.mol
Boiling point: 274.4 °C at 760 mmHg
Storage Temperature: 0-6°C
Flash Point: 119.8 °C
Density: 1.37 g/cm3
Surface Tension: 54.6 dyne/cm
Enthalpy of Vaporization: 49.22 kJ/mol
Vapour Pressure: 0.00907 mmHg at 25°C
XLogP3-AA: 2.7
H-Bond Donor: 0
H-Bond Acceptor: 3
Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| chicken | LD50 | oral | 110mg/kg (110mg/kg) | PERIPHERAL NERVE AND SENSATION: STRUCTURAL CHANGE IN NERVE OR SHEATH BEHAVIORAL: ATAXIA | Bochu Kagaku. Scientific Pest Control. Vol. 40, Pg. 49, 1975. |
| mouse | LD50 | oral | 88mg/kg (88mg/kg) | Agricultural and Biological Chemistry. Vol. 29, Pg. 243, 1965. | |
| mouse | LD50 | skin | > 1250mg/kg (1250mg/kg) | Pesticide Manual. Vol. 9, Pg. 308, 1991. | |
| mouse | LD50 | subcutaneous | 81600ug/kg (81.6mg/kg) | Japan Pesticide Information. Vol. (2), Pg. 30, 1970. | |
| rat | LD50 | oral | 102mg/kg (102mg/kg) | Pesticides. Vol. 15, Pg. 3, 1981. | |
| rat | LD50 | skin | 400mg/kg (400mg/kg) | Farm Chemicals Handbook. Vol. -, Pg. C268, 1991. |
Safety Profile
Poison by ingestion, skin contact, and subcutaneous routes. Mutation data reported. An insecticide. When heated to decomposition it emits very toxic fumes of SOx and POx. See also PARATHION.
Safety Information of 2-Methoxy-4H-1,2,3-benzodioxaphosphorine-2-sulfide (CAS NO.3811-49-2):
Hazard Codes: T.gif){kind=small}
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Risk Statements: 24/25-39/25-51/53
24: Toxic in contact with skin
25: Toxic if swallowed
39: Danger of very serious irreversible effects
51: Toxic to aquatic organisms
53: May cause long-term adverse effects in the aquatic environment
Safety Statements: 36/37-38-45-61
36: Wear suitable protective clothing
37: Wear suitable gloves
38: In case of insufficient ventilation, wear suitable respiratory equipment
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
61: Avoid release to the environment. Refer to special instructions safety data sheet
Specification
2-Methoxy-4H-1,2,3-benzodioxaphosphorine-2-sulfide ,its CAS NO. is 3811-49-2,the synonyms is 2-Methoxy-4H-1,3,2-lambda-5-benzodioxaphosphinine 2-sulphide ; 2-Methoxy-4H-benzo-1,3,2-dioxaphosphorin 2-sulphide ; Phosphorothioic acid, cyclic O,O-(methylene-o-phenylene) O-methyl ester ; Salithion ; 4H-(1.3.2)Benzodioxaphosphorine, 2-methoxy-, 2-sulfide ; Salithion-sumitomo .