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51652-47-2

Basic Information
CAS No.: 51652-47-2
Name: Z-5-DECEN-1-OL
Article Data: 37
Molecular Structure:
Molecular Structure of 51652-47-2 (Z-5-DECEN-1-OL)
Formula: C10H20 O
Molecular Weight: 156.268
Synonyms: 5-Decen-1-ol,(Z)-; (Z)-5-Decen-1-ol; cis-5-Decen-1-ol; cis-5-Decenol
Density: 0.845±0.06 g/cm3 (20 ºC 760 Torr)
Boiling Point: 225.3±0.0℃ (760 Torr)
Flash Point: 87.9±17.8℃
PSA: 20.23000
LogP: 2.89540
Synthetic route
51652-46-1

(Z)-1-(2-tetrahydropyranyloxy)-dec-5-ene

51652-47-2

(Z)-dec-5-en-1-ol

Conditions
ConditionsYield
With pyridinium p-toluenesulfonate In methanol at 50℃; for 2h;100%
With pyridinium p-toluenesulfonate In methanol at 50℃; for 2h;100%
With toluene-4-sulfonic acid In methanol for 6h; Ambient temperature;85%
89625-08-1, 89625-10-5, 115693-87-3, 115693-88-4

(5S,6R)-6-(Diphenyl-phosphinoyl)-decane-1,5-diol

51652-47-2

(Z)-dec-5-en-1-ol

Conditions
ConditionsYield
With sodium hydride In N,N-dimethyl-formamide98%
98%

(5RS,6SR) 6-diphenylphosphinoyldecane-1,5-diol

51652-47-2

(Z)-dec-5-en-1-ol

Conditions
ConditionsYield
With sodium hydride In N,N-dimethyl-formamide at 50℃; for 2h;97.5%
68274-97-5

dec-5-yn-1-ol

51652-47-2

(Z)-dec-5-en-1-ol

Conditions
ConditionsYield
With ethanol; (NCP)IrHCl; tert-butylamine at 85℃; for 72h; Inert atmosphere; Sealed tube; stereoselective reaction;97%
With hydrogen at 40℃; under 760.051 Torr; for 5h; stereoselective reaction;96%
With quinoline; hydrogen In ethyl acetate for 3.5h;92%
79837-87-9

(Z)-5-Decensaeure-methylester

51652-47-2

(Z)-dec-5-en-1-ol

Conditions
ConditionsYield
With diisobutylaluminium hydride In diethyl ether; toluene at 0 - 20℃; for 17h;95%
With lithium aluminium tetrahydride In diethyl ether84%
With lithium aluminium tetrahydride In tetrahydrofuran for 4h; Heating;
67446-07-5

(Z)-5-decenyl acetate

51652-47-2

(Z)-dec-5-en-1-ol

Conditions
ConditionsYield
With potassium hydroxide In methanol for 24h;93%
67773-69-7

(Z)-deca-1,5-diene

51652-47-2

(Z)-dec-5-en-1-ol

Conditions
ConditionsYield
With sodium hydroxide; 9-borabicyclo[3.3.1]nonane dimer; dihydrogen peroxide In tetrahydrofuran; methanol Oxidation;92%
(i) 9-bora-bicyclo<3.3.1>nonane, (ii) H2O2; Multistep reaction;
With sodium hydroxide; 9-borabicyclo[3.3.1]nonane dimer; dihydrogen peroxide 1) 2h, THF; 2) 0 deg C; 3) 50 deg C; Multistep reaction;
With 9-borabicyclo[3.3.1]nonane dimer; hydroxide hydroboration-oxidation;
68274-97-5

dec-5-yn-1-ol

A

51652-47-2

(Z)-dec-5-en-1-ol

B

56578-18-8

(E)-5-decen-1-ol

Conditions
ConditionsYield
With dihydridotetrakis(triphenylphosphine)ruthenium; hydrogen In ethanol at 20℃; for 36h; optical yield given as %de; stereoselective reaction;A 91%
B n/a
21662-08-8

(Z)-dec-5-enal

51652-47-2

(Z)-dec-5-en-1-ol

Conditions
ConditionsYield
With lithium aluminium tetrahydride85%
With lithium aluminium tetrahydride In diethyl ether at 20℃; for 5h;85%
With diisobutylaluminium hydride In diethyl ether; toluene at -10℃; for 1.5h; Yield given;
With diisobutylaluminium hydride In diethyl ether; toluene at -10℃; for 1.5h; Yield given;
132716-07-5, 106335-91-5

(Z)-6-iodo-5-hexene-1-ol

85167-10-8

(s)-pinanediol butylboronate

51652-47-2

(Z)-dec-5-en-1-ol

Conditions
ConditionsYield
Stage #1: (s)-pinanediol butylboronate With sec.-butyllithium In tetrahydrofuran; cyclohexane at -78 - 20℃; for 1.5h; Suzuki-Miyaura reaction;
Stage #2: (Z)-6-iodo-5-hexene-1-ol With sodium acetate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In tetrahydrofuran at 70 - 80℃;
60%
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