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CAS No.: | 53221-14-0 |
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Name: | 2-(2,7-DICHLORO-9H-FLUORENYL-4-YL)OXIRANE |
Article Data: | 4 |
Molecular Structure: | |
Formula: | C15H10Cl2O |
Molecular Weight: | 277.15 |
Synonyms: | 2-(2,7-Dichloro-9H-fluoren-4-yl)-Oxirane |
EINECS: | 922-480-9 |
Density: | 1.449±0.06 g/cm3(Predicted) |
Boiling Point: | 442.0±45.0 °C(Predicted) |
Appearance: | white crystal powder |
PSA: | 12.53000 |
LogP: | 4.63590 |
2-(2,7-dichloro-9H-fluoren-4-yl)oxirane
Conditions | Yield |
---|---|
With sodium methylate at 50 - 60℃; | |
With sodium hydroxide In methanol Reflux; | |
With sodium ethanolate In ethanol Large scale; | 235 kg |
2,7-dichloro-9H-fluorene
2-(2,7-dichloro-9H-fluoren-4-yl)oxirane
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: aluminum (III) chloride / dichloromethane / -5 - 0 °C 2: sodium tetrahydroborate / ethanol / 1 h / -5 - 5 °C 3: sodium methylate / 50 - 60 °C View Scheme | |
Multi-step reaction with 3 steps 1: aluminum (III) chloride / dichloromethane / 0 - 5 °C 2: sodium tetrahydroborate / methanol / 0 - 20 °C 3: sodium hydroxide / methanol / Reflux View Scheme | |
Multi-step reaction with 3 steps 1: aluminum (III) chloride / dichloromethane / 8 h / 0 - 5 °C / Large scale 2: sodium tetrahydroborate / ethanol / 3 h / -5 - 5 °C / Large scale 3: sodium ethanolate / ethanol / Large scale View Scheme |
2-(2,7-dichloro-9H-fluoren-4-yl)oxirane
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: sodium tetrahydroborate / ethanol / 1 h / -5 - 5 °C 2: sodium methylate / 50 - 60 °C View Scheme | |
Multi-step reaction with 2 steps 1: sodium tetrahydroborate / methanol / 0 - 20 °C 2: sodium hydroxide / methanol / Reflux View Scheme | |
Multi-step reaction with 2 steps 1: sodium tetrahydroborate / ethanol / 3 h / -5 - 5 °C / Large scale 2: sodium ethanolate / ethanol / Large scale View Scheme |
9H-fluorene
2-(2,7-dichloro-9H-fluoren-4-yl)oxirane
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1: chlorine / acetic acid / 15 h / 35 - 45 °C 2: aluminum (III) chloride / dichloromethane / -5 - 0 °C 3: sodium tetrahydroborate / ethanol / 1 h / -5 - 5 °C 4: sodium methylate / 50 - 60 °C View Scheme | |
Multi-step reaction with 4 steps 1: chlorine; acetic acid / 40 - 42 °C 2: aluminum (III) chloride / dichloromethane / 0 - 5 °C 3: sodium tetrahydroborate / methanol / 0 - 20 °C 4: sodium hydroxide / methanol / Reflux View Scheme | |
Multi-step reaction with 4 steps 1: hydrogenchloride; chlorine; acetic acid / 10 h / 90 °C / Inert atmosphere; Large scale 2: aluminum (III) chloride / dichloromethane / 8 h / 0 - 5 °C / Large scale 3: sodium tetrahydroborate / ethanol / 3 h / -5 - 5 °C / Large scale 4: sodium ethanolate / ethanol / Large scale View Scheme |
chloro-trimethyl-silane
2-(2,7-dichloro-9H-fluoren-4-yl)oxirane
Conditions | Yield |
---|---|
With zinc(II) oxide In dichloromethane at 20℃; for 2h; | 73% |
2-(2,7-dichloro-9H-fluoren-4-yl)oxirane
dimethyl diselenide
Conditions | Yield |
---|---|
In methanol at 5 - 10℃; Inert atmosphere; | 73% |
2-(2,7-dichloro-9H-fluoren-4-yl)oxirane
dibutylamine
2-dibutylamino-1-(2,7-dichloro-9H-fluoren-4-yl)ethanol
2-(2,7-dichloro-9H-fluoren-4-yl)oxirane
2,7-dichloro-4-[2-(dibutyl amino)-1-hydroxyethyl]-9H-fluoren-9-one
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: ethanol / 15 h / 78 °C 2: sodium hydroxide; oxygen / ethanol / 6 h / 23 - 70 °C View Scheme |
2-(2,7-dichloro-9H-fluoren-4-yl)oxirane
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: ethanol / 15 h / 78 °C 2: sodium hydroxide / ethanol / 6 h / 23 - 70 °C View Scheme |
2-(2,7-dichloro-9H-fluoren-4-yl)oxirane
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1: zinc(II) oxide / dichloromethane / 2 h / 20 °C 2: potassium carbonate / acetonitrile / 16 h / Inert atmosphere; Reflux 3: hydrogenchloride / tetrahydrofuran; water / 50 °C / Inert atmosphere 4: sodium hydroxide / ethanol / 1 h / Inert atmosphere; Reflux; Green chemistry View Scheme |
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Product Name: 2-(2,7-Dichloro-9H-fluoren-4-yl)oxirane
Molecular Structure of 2-(2,7-Dichloro-9H-fluoren-4-yl)oxirane (CAS NO.53221-14-0):
Molecular Formula: C15H10Cl2O
Molecular Weight: 277.15
CAS NO: 53221-14-0