Products Categories
CAS No.: | 603-36-1 |
---|---|
Name: | Triphenylantimony |
Article Data: | 121 |
Molecular Structure: | |
Formula: | C18H15Sb |
Molecular Weight: | 353.067 |
Synonyms: | NSC 2844;Triphenylantimony;Triphenylstibane;Triphenylstibine;BRN 3608108;CCRIS 1300;Trifenylstibin; |
EINECS: | 210-037-6 |
Density: | 1.434 g/cm3 |
Melting Point: | 52-55 °C |
Boiling Point: | 377 °C |
Flash Point: | 109 °C |
Solubility: | insoluble in water |
Appearance: | off-white powder |
Hazard Symbols: | Xn,N |
Risk Codes: | 20/22-51/53 |
Safety: | 61 |
Transport Information: | UN 3467 |
PSA: | 0.00000 |
LogP: | 4.46040 |
tetraphenyl stibonium iodide
triphenylantimony
Conditions | Yield |
---|---|
In water Electrochem. Process; reduction; | 100% |
diphenylfluorostibine
phenyltrifluorosilane
A
triphenylantimony
B
silicon tetrafluoride
Conditions | Yield |
---|---|
reflux for 3 d; | A 100% B n/a |
reflux for 3 d; | A 100% B n/a |
triphenylantimony dichloride
B
triphenylantimony
Conditions | Yield |
---|---|
In toluene a soln. of vanadocene and dichlorotriphenylantimony (2:1) in toluene at room temp. for 20 h, mixt. becomes blue; solvent is removed in vac., triphenylstibine is extd. with hexane, residue consists of dark blue crystals; elem. anal.; | A 98% B 99% |
triphenylantimony dichloride
A
bis(cyclopentadienyl)vanadium dichloride
B
triphenylantimony
Conditions | Yield |
---|---|
In toluene heating of vanadocene and dichlorotriphenylantimony in the ratio of 1:1 in toluene at 100°C for 5 h;; removal of solvent under vac.; the stibine was extd. with hexane;; | A n/a B 99% |
Conditions | Yield |
---|---|
In hexane The complex and a slight excess of Pp are refluxed in hexane for 5 min (N2). Some decompn. was observed.; The reaction soln. was filtered and concd. to small vol. under reduced pressure then subjected to preparative thin layer chromy. (silica gel; light petroleum/diethyl ether).; | A 99% B n/a C n/a |
A
biphenyl
B
diphenyl sulfide
C
triphenylantimony
D
diphenyldisulfane
E
benzene
Conditions | Yield |
---|---|
In neat (no solvent) thermal decompn. of Sb compd. in a sealed tube on heating to 140°C for 3 h; not isolated, detected by GLC and TLC; | A 21% B 69% C 99% D 30% E 6% |
Conditions | Yield |
---|---|
Stage #1: chlorobenzene With cis-Octadecenoic acid; sodium In toluene at 30 - 40℃; for 2h; Inert atmosphere; Stage #2: antimony(III) chloride In toluene at 110℃; for 3.5h; Solvent; Reagent/catalyst; Temperature; Inert atmosphere; | 98.1% |
Conditions | Yield |
---|---|
In tetrachloromethane Kinetics; at 34°C; not isolated, GLC; | A 47% B 5% C 48% D 98% |
In chloroform-d1 Kinetics; at 34°C; not isolated, GLC; | A 35% B 5% C 64% D 95% |
A
4-Methoxybenzenethiol
B
biphenyl
C
4,4'-dimethoxyphenyl disulfide
D
triphenylantimony
Conditions | Yield |
---|---|
In neat (no solvent) 130°C; not isolated, GLC; | A 69% B 17% C 28% D 98% |
In cyclohexene reflux; not isolated, GLC; | A 80% B 12% C 18% D 98% |
In benzene reflux; not isolated, GLC; | A 86% B 4% C 8% D 95% |
In chloroform reflux; not isolated, GLC; | A 70% B 4% C 19% D 95% |
A
biphenyl
B
4,4'-dimethoxyphenyl disulfide
C
1-methoxy-4-(phenylsulfanyl)benzene
D
triphenylantimony
E
benzene
Conditions | Yield |
---|---|
In neat (no solvent) thermal decompn. of Sb compd. in a sealed tube on heating to 140°C for 3 h; not isolated, detected by GLC and TLC; | A 17% B 28% C 69% D 98% E 13% |
Triphenylstibane (603-36-1)and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory.
OSHA PEL: TWA 0.5 mg(Sb)/m3
ACGIH TLV: TWA 0.5 mg(Sb)/m3
NIOSH REL: (Antimony) TWA 0.5 mg(Sb)/m3
The Triphenyl stibine with CAS registry number of 603-36-1 is also known as Stibine, triphenyl-. The IUPAC name is Triphenylstibane. It belongs to product categories of Classes of Metal Compounds; Sb (Antimony) Compounds; Semimetal Compounds. Its EINECS registry number is 210-037-6. In addition, the formula is C18H15Sb and the molecular weight is 353.08. This chemical is a off-white powder and should be stored in sealed containers.
Physical properties about Triphenyl stibine are: (1)Rotatable Bond Count: 3; (2)Exact Mass: 352.021193; (3)MonoIsotopic Mass: 352.021193; (4)Topological Polar Surface Area: 0; (5)Heavy Atom Count: 19; (6)Formal Charge: 0; (7)Complexity: 202.
Uses of Triphenyl stibine: it is used as catalyst for reaction of changing leukotriene into aromatic and hydrogenated aromatic. This chemical is also used as inhibitors for polymerization, lubricant additives and used in dechlorination.
When you are using this chemical, please be cautious about it. As a chemical, it is harmful by inhalation and if swallowed. What's more, it is toxic to aquatic organisms and may cause long-term adverse effects in the aquatic environment. During using it, avoid release to the environment refer to special instructions/safety data sheet.
You can still convert the following datas into molecular structure:
1. SMILES: c3c([Sb](c1ccccc1)c2ccccc2)cccc3
2. InChI: InChI=1/3C6H5.Sb/c3*1-2-4-6-5-3-1;/h3*1-5H;/rC18H15Sb/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H
3. InChIKey: HVYVMSPIJIWUNA-KWOBPOEBAA
4. Std. InChI: InChI=1S/3C6H5.Sb/c3*1-2-4-6-5-3-1;/h3*1-5H;
5. Std. InChIKey: HVYVMSPIJIWUNA-UHFFFAOYSA-N
The toxicity data is as follows:
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
mouse | LD50 | oral | 650mg/kg (650mg/kg) | Aerospace Medical Research Laboratory Report. Vol. TR-74-78, Pg. 1974, | |
mouse | LDLo | intraperitoneal | 500mg/kg (500mg/kg) | "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. Vol. 6, Pg. 229, 1954. | |
rat | LD50 | intraperitoneal | 168mg/kg (168mg/kg) | Aerospace Medical Research Laboratory Report. Vol. TR-74-78, Pg. 1974, | |
rat | LD50 | oral | 183mg/kg (183mg/kg) | "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986Vol. -, Pg. 1280, 1986. |