Products Categories
Basic Information
| CAS No.: | 620-71-3 |
|---|---|
| Name: | PROPIONANILIDE |
| Article Data: | 237 |
| Molecular Structure: | |
|
|
|
| Formula: | C9H11 N O |
| Molecular Weight: | 149.192 |
| Synonyms: | Propionanilide(6CI,7CI,8CI); N-Phenylpropanamide; N-Phenylpropionamide; NSC 58952; R 50977 |
| Density: | 1.073g/cm3 |
| Melting Point: | 104-107℃ |
| Boiling Point: | 314.4°C at 760 mmHg |
| Flash Point: | 182°C |
| Solubility: | Insoluble in water. |
| Safety: | Moderately toxic by ingestion. When heated to decomposition it emits toxic fumes of NOx. |
| PSA: | 29.10000 |
| LogP: | 2.10810 |
Related products
- 81281-59-67-Benzylideneaminotheophylline
- 82993-81-5D-threo-Ritalinic acid hydrochloride
- 73441-42-6METHYL-5-CHLORO-2,2-DIMETHYLVALERATE
- 68439-39-4Poly(oxy-1,2-ethanediyl), alpha-(2-ethylhexyl)-omega-hydroxy-,
- 852475-26-4MC1568
- 958254-66-51H-Imidazo[4,5-b]pyridine-2-carboxaldehyde, 1-methyl-, hydrochloride
- 99170-93-1N-Methyl-2-oxazolamine
- 717878-06-31-(4-fluorophenyl)-4-nitro-1H-imidazole
- 914458-26-7[5-(2-fluorophenyl)-1-pentyl-1H-pyrrol-3-yl]-1-naphthalenyl-Methanone
- 894852-01-87-BROMO-2,2-DIMETHYL-2H-PYRIDO[3,2-B][1,4]OXAZIN-3(4H)-ONE
Synthetic route
- 23517-42-2
propiophenone oxime
- 620-71-3
N-(phenyl)-2-methylacetamide
Conditions
| Conditions | Yield |
|---|---|
| With sulfuric acid; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate for 0.0166667h; Beckmann rearrangement; microwave irradiation; | 100% |
| mercury dichloride In acetonitrile at 80℃; for 8h; Beckmann rearrangement; | 98% |
| With bis-(2-oxo-3-oxazolidinyl)phosphoryl chloride; zinc(II) chloride In acetonitrile for 1h; Beckmann rearrangement; Heating; | 97% |
Conditions
| Conditions | Yield |
|---|---|
| With 1,1'-carbonyldiimidazole; methyl iodide In acetonitrile for 1h; Heating; | 98% |
| With p-toluenesulfonyl chloride; zinc(II) chloride In acetonitrile for 1h; Beckmann rearrangement; Inert atmosphere; Reflux; | 98% |
| With silica gel; caesium carbonate; N-tosylimidazole In N,N-dimethyl-formamide for 2h; Beckmann rearrangement; Reflux; | 98% |
Conditions
| Conditions | Yield |
|---|---|
| With fluorosulfonyl fluoride; N-ethyl-N,N-diisopropylamine In acetonitrile at 20℃; for 5h; | 98% |
| Stage #1: propionic acid With iodine; triethylamine; phosphorous acid trimethyl ester In dichloromethane for 0.166667h; Cooling with ice; Inert atmosphere; Stage #2: aniline In dichloromethane at 20℃; for 3h; Inert atmosphere; Cooling with ice; | 96% |
| With [((CH3)5Cp)2Zr(H2O)2OSO2C8F17]+[OSO2C8F17]-*THF In neat (no solvent) at 80℃; for 2h; | 94% |
Conditions
| Conditions | Yield |
|---|---|
| With palladium(II) acetylacetonate In toluene at 100℃; under 30003 Torr; for 20h; Autoclave; Inert atmosphere; regioselective reaction; | 98% |
| With C52H52NO5P; palladium(II) iodide In tetrahydrofuran at 60℃; under 760.051 Torr; for 72h; Autoclave; regioselective reaction; | 93% |
| With Ru-clusters supported on ceria In tetrahydrofuran at 160℃; under 7500.75 Torr; for 24h; Autoclave; | 67% |
| Co/C In water at 150℃; under 53203.6 Torr; for 72h; | 54% |
...Expand
- 369-57-3
benzenediazonium tetrafluoroborate
- 107-12-0
propiononitrile
- 620-71-3
N-(phenyl)-2-methylacetamide
Conditions
| Conditions | Yield |
|---|---|
| Stage #1: benzenediazonium tetrafluoroborate; propiononitrile for 0.0166667h; Microwave irradiation; Stage #2: With water In diethyl ether | 97% |
Conditions
| Conditions | Yield |
|---|---|
| With oxygen; sodium hydroxide In water at 40℃; for 24h; | 97% |
| With oxygen; sodium hydroxide In water at 40℃; for 24h; Green chemistry; | 94% |
| With potassium tert-butylate In 1,4-dioxane at 110℃; for 24h; | 88% |
Conditions
| Conditions | Yield |
|---|---|
| With tris(pentafluorophenyl)borate In neat (no solvent) at 20℃; for 0.0333333h; Green chemistry; | 96% |
| With sodium dodecyl-sulfate In water | 87% |
Conditions
| Conditions | Yield |
|---|---|
| With trifluorormethanesulfonic acid; hydroxylamine hydrochloride In formic acid for 7h; Heating; | 96% |
| With sodium azide; sulfuric acid; silica gel at 60℃; for 0.5h; Schmidt reaction; | 95% |
| With zinc(II) chloride; hydroxylamine-O-sulfonic acid In water at 20℃; for 16h; Beckmann Rearrangement; | 93% |
Conditions
| Conditions | Yield |
|---|---|
| With triphenylphosphine In benzene for 60h; Heating; | 96% |
| With triethylphosphine In benzene at 80℃; for 12h; | 87% |
Conditions
| Conditions | Yield |
|---|---|
| With hydrogen for 1h; | 94% |
Raw Materials
- Total:20 Page 1 of 1 1
Post a RFQ
1
What can I do for you?
Get Best Price
Get Best Price for 620-71-3
PROPIONANILIDE
Chemistry
Propionanilide is also named as n-phenyl-propanamid;N-Phenylpropanamide;Propionamide, N-phenyl-;Propionic anilide,and so on.
Molecular Formula: C9H11NO
Molecular Weight: 149.19
EINECS: 210-649-3
Toxicity Data With Reference
Test type: LD50 - Lethal dose, 50 percent kill
Contact: Oral
Species: Rodent - mouse
Dose: 1100 mg/kg
Toxic effect:Details of toxic effects not reported other than lethal dose value
Referrence: TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 19,20,1971
RTECS:UE4600000
Consensus Reports
Reported in EPA TSCA Inventory.
EPA TSCA Section 8(b) CHEMICAL INVENTORY EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, JUNE 1998
Safety Profile
Propionanilide is moderately toxic by ingestion. When heated to decomposition it emits toxic fumes of NOx.