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72715-02-7

Basic Information
CAS No.: 72715-02-7
Name: Ilicol
Molecular Structure:
Molecular Structure of 72715-02-7 (Ilicol)
Formula: C15H26O2
Molecular Weight: 238.37
Synonyms: ilicic alcohol;Gilvocacin V;gilvocarcin V;
Density: 1.029±0.06 g/cm3(Predicted)
Melting Point: 134-135 °C
Boiling Point: 350.9±25.0 °C(Predicted)
PSA: 40.46000
LogP: 2.89240
Synthetic route
4586-68-9

4-hydroxy-11(13)-eudesmen-12-oic acid

72715-02-7

(1R,4aR,7R,8aR)-decahydro-7-(3-hydroxyprop-1-en-2-yl)-1,4a-dimethylnaphthalen-1-ol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In tetrahydrofuran
72715-02-7

(1R,4aR,7R,8aR)-decahydro-7-(3-hydroxyprop-1-en-2-yl)-1,4a-dimethylnaphthalen-1-ol

72715-06-1

4α-hydroxyeudesm-11-en-12-al

Conditions
ConditionsYield
With jones reagent87%
With chromium(VI) oxide; sulfuric acid In acetone
With Jones reagent
108-24-7

acetic anhydride

72715-02-7

(1R,4aR,7R,8aR)-decahydro-7-(3-hydroxyprop-1-en-2-yl)-1,4a-dimethylnaphthalen-1-ol

72715-07-2

12-acetoxy-4α-hydroxyeudesm-11(13)-ene

Conditions
ConditionsYield
With pyridine for 12h;
72715-02-7

(1R,4aR,7R,8aR)-decahydro-7-(3-hydroxyprop-1-en-2-yl)-1,4a-dimethylnaphthalen-1-ol

16641-46-6

Selinan-4α-ol

Conditions
ConditionsYield
With hydrogen; palladium on activated charcoal In ethyl acetate
72715-02-7

(1R,4aR,7R,8aR)-decahydro-7-(3-hydroxyprop-1-en-2-yl)-1,4a-dimethylnaphthalen-1-ol

2-((2R,4aR,8R,8aR)-4a,8-Dimethyl-8-trimethylsilanyloxy-decahydro-naphthalen-2-yl)-propenal

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 87 percent / Jones reagent
2: 91 percent / HMDS / CH2Cl2 / 20 °C
View Scheme
72715-02-7

(1R,4aR,7R,8aR)-decahydro-7-(3-hydroxyprop-1-en-2-yl)-1,4a-dimethylnaphthalen-1-ol

Trifluoro-acetic acid (1R,4aR,7R,8aR)-7-(1-formyl-vinyl)-1,4a-dimethyl-decahydro-naphthalen-1-yl ester

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 87 percent / Jones reagent
2: 92 percent / pyridine; DMAP / 20 °C
View Scheme
72715-02-7

(1R,4aR,7R,8aR)-decahydro-7-(3-hydroxyprop-1-en-2-yl)-1,4a-dimethylnaphthalen-1-ol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 87 percent / Jones reagent
2: 56 percent / POCl3; pyridine / -20 °C
View Scheme
72715-02-7

(1R,4aR,7R,8aR)-decahydro-7-(3-hydroxyprop-1-en-2-yl)-1,4a-dimethylnaphthalen-1-ol

iso-β-costal

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 87 percent / Jones reagent
2: 93 percent / p-TsOH; MS 4A / benzene / 80 °C
View Scheme
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